Synthesis of five-and six-membered heterocycles by dimethyl carbonate with catalytic amounts of nitrogen bicyclic bases

F Arico, S Evaristo, P Tundo - Green Chemistry, 2015 - pubs.rsc.org
A catalytic amount of a nitrogen bicyclic base, ie, DABCO, DBU or TBD, is effective for the
one-pot synthesis of heterocycles from 1, 4-, 1, 5-diols and 1, 4-bifunctional compounds via …

5-Membered N-heterocyclic compounds by dimethyl carbonate chemistry

F Arico, U Toniolo, P Tundo - Green Chemistry, 2012 - pubs.rsc.org
Aliphatic and aromatic 1, 4-bifunctional compounds bearing a primary alcoholic function and
an amine can be efficiently cyclised with dimethyl carbonates in the presence of a base to …

Synthesis of five‐membered cyclic ethers by reaction of 1, 4‐diols with dimethyl carbonate

F Aricò, P Tundo, A Maranzana, G Tonachini - ChemSusChem, 2012 - Wiley Online Library
Abstract The reaction of 1, 4‐diols with dimethyl carbonate in the presence of a base led to
selective and high‐yielding syntheses of related five‐membered cyclic ethers. This synthetic …

Dialkyl carbonates in the green synthesis of heterocycles

P Tundo, M Musolino, F Aricò - Frontiers in Chemistry, 2019 - frontiersin.org
This review focuses on the use of dialkyl carbonates (DACs) as green reagents and solvents
for the synthesis of several 5-and 6-membered heterocycles including: tetrahydrofuran and …

Facile and efficient synthesis of cyclic anhydrides from dicarboxylic acids

C Robert, F de Montigny, CM Thomas - ACS Catalysis, 2014 - ACS Publications
An efficient, high-yielding sustainable route to cyclic anhydrides from biorenewable and
inexpensive dicarboxylic acids has been developed. Cyclic anhydrides were synthesized …

Carbon dioxide-based facile synthesis of cyclic carbamates from amino alcohols

T Niemi, I Fernández, B Steadman… - Chemical …, 2018 - pubs.rsc.org
We report herein a straightforward general method for the synthesis of cyclic carbamates
from amino alcohols and carbon dioxide in the presence of an external base and a hydroxyl …

Dimethyl Carbonate as a Sacrificial Molecule for the Synthesis of 5‐Memebered N‐ and O‐Heterocycles

F Arico, P Tundo - Journal of the Chinese Chemical Society, 2012 - Wiley Online Library
In the last twenty years DMC has been employed as an efficient methylating and
methoxycarbonylating agent with several monodentate and bidentate nucleophiles, showing …

Recent progress in the cyclization reactions using carbon dioxide

W Zhang, N Zhang, C Guo, X Lü - Chinese Journal of Organic …, 2017 - sioc-journal.cn
Carbon dioxide is a cheap, abundant and renewable C 1 feedstock. Methodology study on
the transformation of carbon dioxide into highly value-added chemicals has become one of …

Tandem reactions based on the cyclization of carbon dioxide and propargylic alcohols: Derivative applications of α-Alkylidene carbonates

B Jiang, X Yan, Y Xu, N Likhanova, HD Velázquez… - Catalysts, 2022 - mdpi.com
As a well-known greenhouse gas, carbon dioxide (CO2) has attracted increasing levels of
attention in areas of energy, environment, climate, etc. Notably, CO2 is an abundant …

Intramolecular etherification of five-membered cyclic carbonates bearing hydroxyalkyl groups

KM Tomczyk, PA Guńka, PG Parzuchowski… - Green …, 2012 - pubs.rsc.org
We report a new one-pot synthetic route to tetrahydrofuran derivatives, which were
unexpectedly produced under basic conditions by intramolecular etherification of substituted …