AT‐shaped NiI complex was synthesized using a rigid acridane‐based pincer ligand to
prepare a metalloradical center. Structural data displays a nickel ion is embedded in the …

Studies on N2 activation and transformation by transition metal hydride complexes are of
particular interest and importance. The synthesis and diverse transformations of a dinitrogen …

Conspectus Low-valent, low-coordinate 3d metal complexes represent a class of
extraordinarily reactive compounds that can act as reagents and catalysts for challenging …

The dinickel (II) dihydride complex (1K) of a pyrazolate‐based compartmental ligand with β‐
diketiminato (nacnac) chelate arms (L−), providing two pincer‐type {N3} binding pockets …

We report the reactivity and characterization of hydride, methyl, and bromo NiII complexes
with a new class of electron-rich and sterically hindered PNP pincer ligands, Me4PNPR (R …

A nickel nickel‐bonded complex,[{Ni (μ‐L.−)} 2](1; L=[(2, 6‐iPr2C6H3) NC (Me)] 2), was
synthesized from reduction of the LNiBr2 precursor by sodium metal. Further controllable …

Amidate‐supported two‐and three‐coordinate NiI complexes were synthesized by reduction
of the corresponding NiII precursors. A dramatic change in binding mode is observed upon …

Pincer‐type nickel–aluminum complexes were synthesized using two equivalents of the
phosphinoamide,[PhNCH2PiPr2]−. The Ni0–AlIII complexes,{(MesPAlP) Ni} 2 (μ‐N2) and …

Herein, we report the isolation and a reactivity study of the first example of an elusive
palladium (II) terminal imido complex. This scaffold is an alleged key intermediate for various …

A new class of chiral C 2-symmetric N-donor pincer ligands, 2, 5-bis (2-
oxazolinyldimethylmethyl) pyrroles (PdmBox) H, was synthesized starting from the readily …