Thermodynamic study of hydrogen bonding by means of gas-liquid chromatography

DE Martire, P Riedl - The Journal of Physical Chemistry, 1968 - ACS Publications
Introduction It is now well established that gas-liquid chromatography is an effective and
advantageous method for studying the thermodynamics of nonelectrolytic solu-tions. Most of …

Thermodynamics of molecular association by gas-liquid chromatography. Comparison of two experimental approaches

HL Liao, DE Martire, JP Sheridan - Analytical Chemistry, 1973 - ACS Publications
Two approaches have been developed and used for the gas-liquid chromatographic
measurement of organic complex formation constants, one in our laboratory and the otherin …

Hydrogen bonding. Part 13. A new method for the characterisation of GLC stationary phases—the laffort data set

MH Abraham, GS Whiting, RM Doherty… - Journal of the Chemical …, 1990 - pubs.rsc.org
A number of equations for the correlation of retention data for a series of solutes on a given
stationary phase (or solvent) have been investigated with the aim of characterising …

Hydrogen bonding: XVII. The characterisation of 24 gas-liquid chromatographic stationary phases studied by Poole and co-workers. including molten salts, and …

MH Abraham, GS Whiting, RM Doherty… - … of Chromatography A, 1991 - Elsevier
The general solvation equation log K= c+ rR 2+ sπ 2 H+ aα 2 H+ bβ 2 H+ l log L 16 has
been used to characterise 24 gas-liquid chromatographic stationary phases for which Poole …

Solution Thermodynamics from Gas-Liquid Chromatography.

RE Pecsar, JJ Martin - Analytical Chemistry, 1966 - ACS Publications
Gas-liquid chromatography has been employed to study the thermodynamic solution
properties of two-component volatile nonelectrolyte solutions at infinite dilution. The expres …

Thermodynamics of hydrogen bonding polymer‐solute interactions by inverse gas chromatography

G DiPaola‐Baranyi, JE Guillet… - Die Makromolekulare …, 1980 - Wiley Online Library
The gaschromatographic retention behaviour of a series of solutes with potential hydrogen
bonding activity has been studied, using polyethylene, poly (ethylene‐vinyl acetate), poly …

Pair-wise interactions by gas chromatography: I. Interaction free enthalpies of solutes with non-associated primary alcohol groups

KS Reddy, JC Dutoit - Journal of Chromatography A, 1992 - Elsevier
A method is presented for the determination of interaction free enthalpies between an
interacting group, X, suspended in a paraffin solvent at ideal dilution and a volatile …

Thermodynamic interactions in polymer systems by gas-liquid chromatography. IV. Interactions between components in a mixed stationary phase

DD Deshpande, D Patterson, HP Schreiber… - Macromolecules, 1974 - ACS Publications
The glc method of determining specific retention times of a vapor-phase probe in a
polymeric sta-tionary phase is used to measure the thermodynamic interaction between the …

The use of gas-liquid chromatography for the determination of thermodynamic properties

CL Young - Chromatographic Reviews, 1968 - Elsevier
In the previous section it was shown that, in principle, mixed second virial coefficients and
activity coefficients can be obtained from GLC retention volume data. Before the method can …

Thermodynamics of molecular association by gas-liquid chromatography. VII. Hydrogen bonding of aliphatic alcohols to di-n-octyl ether, di-n-octyl thioether, and di-n …

HL Liao, DE Martire - Journal of the American Chemical Society, 1974 - ACS Publications
Conclusions Our researches on the volume changes which accom-pany the selective
bindingof ions bypolyelectrolyte gels have led us to the following tentativeconclusions.(1) …