High-Performance n-Type PbSe–Cu2Se Thermoelectrics through Conduction Band Engineering and Phonon Softening

C Zhou, Y Yu, YK Lee, O Cojocaru-Mirédin… - Journal of the …, 2018 - ACS Publications
From a structural and economic perspective, tellurium-free PbSe can be an attractive
alternative to its more expensive isostructural analogue of PbTe for intermediate …

All-scale hierarchically structured p-type PbSe alloys with high thermoelectric performance enabled by improved band degeneracy

G Tan, S Hao, S Cai, TP Bailey, Z Luo… - Journal of the …, 2019 - ACS Publications
We show an example of hierarchically designing electronic bands of PbSe toward excellent
thermoelectric performance. We find that alloying 15 mol% PbTe into PbSe causes a …

Nanoscale defect structures advancing high performance n-type PbSe thermoelectrics

C Zhou, I Chung - Coordination Chemistry Reviews, 2020 - Elsevier
This short review discusses recent advances in n-type PbSe-based bulk thermoelectric
materials. Their performance has rapidly progressed recently and emerges as one of most …

Exceptionally high average power factor and thermoelectric figure of merit in n-type PbSe by the dual incorporation of Cu and Te

C Zhou, Y Yu, YL Lee, B Ge, W Lu… - Journal of the …, 2020 - ACS Publications
Thermoelectric materials with high average power factor and thermoelectric figure of merit
(ZT) has been a sought-after goal. Here, we report new n-type thermoelectric system Cu x …

Improving the thermoelectric performance of p-type PbSe via synergistically enhancing the Seebeck coefficient and reducing electronic thermal conductivity

Z Huang, D Wang, C Li, J Wang, G Wang… - Journal of Materials …, 2020 - pubs.rsc.org
In this work, the thermoelectric performance of p-type PbSe was improved dramatically by
enhancing the Seebeck coefficient and reducing electronic thermal conductivity through …

Ultrahigh carrier mobility contributes to remarkably enhanced thermoelectric performance in n-type PbSe

Y Xiao, L Xu, T Hong, H Shi, S Wang, X Gao… - Energy & …, 2022 - pubs.rsc.org
A high average ZT value (ZTave) of∼ 1.13 in an n-type PbSe-based thermoelectric material
at 300–873 K has been achieved in this work. Its high thermoelectric performance originates …

Exploring the doping effects of Ag in p-type PbSe compounds with enhanced thermoelectric performance

S Wang, G Zheng, T Luo, X She, H Li… - Journal of Physics D …, 2011 - iopscience.iop.org
In this study, we prepared a series of Ag-doped PbSe bulk materials by a melting–
quenching process combined with a subsequent spark plasma sintering process, and …

Defect engineering for high-performance n-type PbSe thermoelectrics

C Zhou, YK Lee, J Cha, B Yoo, SP Cho… - Journal of the …, 2018 - ACS Publications
Introducing structural defects such as vacancies, nanoprecipitates, and dislocations is a
proven means of reducing lattice thermal conductivity. However, these defects tend to be …

Dense dislocations enable high-performance PbSe thermoelectric at low-medium temperatures

L Xu, Y Xiao, S Wang, B Cui, D Wu, X Ding… - Nature …, 2022 - nature.com
PbSe-based thermoelectric materials exhibit promising ZT values at medium temperature,
but its near-room-temperature thermoelectric properties are overlooked, thus restricting its …

Soft phonon modes from off-center Ge atoms lead to ultralow thermal conductivity and superior thermoelectric performance in n-type PbSe–GeSe

ZZ Luo, S Hao, X Zhang, X Hua, S Cai, G Tan… - Energy & …, 2018 - pubs.rsc.org
Historically PbSe has underperformed PbTe in thermoelectric efficiency and has been
regarded as an inferior relative to its telluride congener. However, the fifty-fold greater …