Probing the pore structure of a chiral periodic mesoporous organosilica using liquid crystals

V Jayalakshmi, T Wood, R Basu, J Du… - Journal of Materials …, 2012 - pubs.rsc.org
Periodic mesoporous organosilicas (PMO) are prepared by the surfactant-templated
condensation of bridged organosilsesquioxane monomers. By controlling the nature of the …

Installing stable molecular chirality within the walls of periodic mesoporous organosilicas via self-assembly

LM Reid, CM Crudden - Chemistry of Materials, 2016 - ACS Publications
The synthesis of highly ordered chiral periodic mesoporous organosilica (PMO) materials is
described using a novel approach. Chiral dopants featuring removable chirality were …

[引用][C] Synthesis and characterization of chiral periodic mesoporous organosilicas

X Meng, T Yokoi, D Lu, T Tatsumi - Angewandte Chemie, 2007 - Wiley Online Library
Chirality is an important topic both in fundamental research and for practical applications in
fields as diverse as biology, functional materials, fine chemistry, and pharmacy. Some …

Chiral periodic mesoporous organosilicates based on axially chiral monomers: transmission of chirality in the solid state

S MacQuarrie, MP Thompson, A Blanc… - Journal of the …, 2008 - ACS Publications
Chiral mesoporous materials have been prepared with purely organic monomers employing
an enantiomerically pure biphenyl bis-siloxane as a dopant along with simple 4, 4′-bis …

Functionalized periodic mesoporous organosilicas: Hierarchical and chiral materials

QH Yang, J Liu, L Zhang - Science China Chemistry, 2010 - Springer
The integration of organic and inorganic fragments within the pore walls of the periodic
mesoporous organosilicas (PMOs) represents one of the recent breakthroughs in material …

Chiral periodic mesoporous organosilicas: Probing chiral induction in the solid state

MWA MacLean, TK Wood, G Wu… - Chemistry of …, 2014 - ACS Publications
The production of a variety of PMO materials made with 1, 1′-biphenylene monomers, and
the inclusion of 1, 1′-binaphthalene dopants is described. The effect of the point of …

Mesostructure-controlled synthesis of chiral norbornane-bridged periodic mesoporous organosilicas

TT Hao, JY Shi, TY Zhuang, WD Wang, FC Li… - Rsc Advances, 2012 - pubs.rsc.org
In this contribution, chiral periodic mesoporous organosilica (PMO) materials with three-
dimensional body-centered (Im3m) and face-centered (Fm3m) cubic mesostructures were …

Synthesis and Characterization of Chiral Benzylic Ether‐Bridged Periodic Mesoporous Organosilicas

J Morell, S Chatterjee, PJ Klar… - … A European Journal, 2008 - Wiley Online Library
The first synthesis of a chiral periodic mesoporous organosilica (PMO) carrying benzylic
ether bridging groups is reported. By hydrolysis and condensation of the new designed …

[PDF][PDF] A 2D-rectangular p2gg silica mesoporous crystal with elliptical mesopores: An intermediate phase of chiral and lamellar mesostructures

H Qiu, Y Sakamoto, O Terasaki, S Che - Advanced Materials, 2008 - academia.edu
Since the pioneering work of Kresge and co-workers,[1, 2] much effort has been devoted to
surfactant-templated mesoporous materials that display topologies closely related to those …

Organosilicas with chiral bridges and self-generating mesoporosity

A Ide, R Voss, G Scholz, GA Ozin… - Chemistry of …, 2007 - ACS Publications
Amine-functionalized, chiral mesoporous organosilicas were prepared from a rationally
designed precursor, which combines the functions of a network builder, a chiral latent …