Small Molecule Chemistry of the Pyrazolylborate−Zinc Unit TpCum,MeZn
M Ruf, H Vahrenkamp - Inorganic chemistry, 1996 - ACS Publications
The synthesis of the highly encapsulating pyrazolylborate ligand hydrotris (3-p-cumenyl-5-
methylpyrazolyl) borate (L= TpCum, Me) and of its zinc hydroxide complex L⊙ Zn− OH (1) …
methylpyrazolyl) borate (L= TpCum, Me) and of its zinc hydroxide complex L⊙ Zn− OH (1) …
Pyrazolylborate− Zinc Alkoxide Complexes. 1. Basic Properties, Methylations, and Heterocumulene Insertions
H Brombacher, H Vahrenkamp - Inorganic chemistry, 2004 - ACS Publications
While a solution of TpPh, MeZn− OH in methanol contains only traces of TpPh, MeZn− OMe,
according to the equilibrium constant K= 5.8× 10-4, the reactions of TpPh, MeZn− OH with …
according to the equilibrium constant K= 5.8× 10-4, the reactions of TpPh, MeZn− OH with …
On the ligating properties of sulfonate and perchlorate anions towards zinc
T Brandsch, FA Schell, K Weis, M Ruf… - Chemische …, 1997 - Wiley Online Library
Attempts are reported to incorporate sulfonate and perchlorate anions as ligands in zinc
complexes of tripodal ligands. Using tris (benzimidazolylmethyl) amine (BIMA) only the aqua …
complexes of tripodal ligands. Using tris (benzimidazolylmethyl) amine (BIMA) only the aqua …
Zinc pyrazolylborate complexes with phenoxide and alkoxide ligands
R Walz, K Weis, M Ruf, H Vahrenkamp - Chemische Berichte, 1997 - Wiley Online Library
The zinc hydroxide complexes Tp* Zn‐OH of highly substituted pyrazolylborate ligands react
with phenols, and alcohols, of sufficient acidity, in a condensation reaction with release of …
with phenols, and alcohols, of sufficient acidity, in a condensation reaction with release of …
Pyrazolylborate− zinc− hydrosulfide complexes and their reactions
M Rombach, H Vahrenkamp - Inorganic Chemistry, 2001 - ACS Publications
Four new hydrosulfide complexes Tp* Zn− SH of substituted pyrazolylborate ligands (Tp*)
were prepared by reactions of Tp* Zn− OH with H2S, and three of them were structurally …
were prepared by reactions of Tp* Zn− OH with H2S, and three of them were structurally …
Tris (pyrazolyl) methanesulfonates: More Than Just Analogues of Tris (pyrazolyl) borate Ligands; N, N, N‐, N, N, O‐, and Other Coordination Modes
W Kläui, M Berghahn, W Frank, GJ Reiß… - European Journal of …, 2003 - Wiley Online Library
The thallium (I) salts of tris (pyrazolyl) methanesulfonate (Tpms) and tris (3-tert-
butylpyrazolyl) methanesulfonate (TpmstBu) have been used to prepare the following …
butylpyrazolyl) methanesulfonate (TpmstBu) have been used to prepare the following …
Hydrotris (methimazolyl) borate, a soft analogue of hydrotris (pyrazolyl) borate. Preparation and crystal structure of a novel zinc complex
M Garner, J Reglinski, I Cassidy, MD Spicer… - Chemical …, 1996 - pubs.rsc.org
Preparation and crystal structure of a novel zinc complex Page 1 Hydrotris(methimazolyl)borate,
a soft analogue of hydrotris(pyrazoly1)borate. Preparation and crystal structure of a novel …
a soft analogue of hydrotris(pyrazoly1)borate. Preparation and crystal structure of a novel …
Homoleptic Group 12 Metal Bis(mercaptoimidazolyl)borate Complexes M(BmR)2 (M = Zn, Cd, Hg)
HM Alvarez, TB Tran, MA Richter… - Inorganic …, 2003 - ACS Publications
The sodium salt of the bis (2-mercapto-1-methylimidazolyl) borate anion [BmMe]-and those
of the new bis (2-mercapto-1-alkylimidazolyl) borates [BmR]-(R= Bz, But, p-Tol) have been …
of the new bis (2-mercapto-1-alkylimidazolyl) borates [BmR]-(R= Bz, But, p-Tol) have been …
Three-coordinate thiolato complexes of zinc: solution and solid-state structures and EHMO analysis of the bonding pattern of [Zn (S-tert-Bu3C6H2-2, 4, 6) 2] 2
M Bochmann, G Bwembya, R Grinter, J Lu… - Inorganic …, 1993 - ACS Publications
Neutral thiolato complexes of zinc and cadmium [M (SR) 2]„form ingeneral infinite lattices
with bridging ligands and tetrahedrally coordinated metal centers. 1 The degree of asso …
with bridging ligands and tetrahedrally coordinated metal centers. 1 The degree of asso …
Chemical Interconversions in the System TP*Zn/CO2/Alcohol [Tp* = Substituted Tris(pyrazolyl)borate]
M Ruf, FA Schell, R Walz… - Chemische Berichte, 1997 - Wiley Online Library
The zinc hydroxide complexes Tp* Zn–OH with TpCum, Me= tris (3‐cumenyl‐5‐
methylpyrazolyl) borate and TptBu, Me= tris (3‐tert‐butyl‐5‐methylpyrazolyl) borate can be …
methylpyrazolyl) borate and TptBu, Me= tris (3‐tert‐butyl‐5‐methylpyrazolyl) borate can be …