Chiral periodic mesoporous organosilicates based on axially chiral monomers: transmission of chirality in the solid state

S MacQuarrie, MP Thompson, A Blanc… - Journal of the …, 2008 - ACS Publications
Chiral mesoporous materials have been prepared with purely organic monomers employing
an enantiomerically pure biphenyl bis-siloxane as a dopant along with simple 4, 4′-bis …

Chiral periodic mesoporous organosilicas: Probing chiral induction in the solid state

MWA MacLean, TK Wood, G Wu… - Chemistry of …, 2014 - ACS Publications
The production of a variety of PMO materials made with 1, 1′-biphenylene monomers, and
the inclusion of 1, 1′-binaphthalene dopants is described. The effect of the point of …

Organosilicas with chiral bridges and self-generating mesoporosity

A Ide, R Voss, G Scholz, GA Ozin… - Chemistry of …, 2007 - ACS Publications
Amine-functionalized, chiral mesoporous organosilicas were prepared from a rationally
designed precursor, which combines the functions of a network builder, a chiral latent …

[引用][C] Synthesis and characterization of chiral periodic mesoporous organosilicas

X Meng, T Yokoi, D Lu, T Tatsumi - Angewandte Chemie, 2007 - Wiley Online Library
Chirality is an important topic both in fundamental research and for practical applications in
fields as diverse as biology, functional materials, fine chemistry, and pharmacy. Some …

Probing the pore structure of a chiral periodic mesoporous organosilica using liquid crystals

V Jayalakshmi, T Wood, R Basu, J Du… - Journal of Materials …, 2012 - pubs.rsc.org
Periodic mesoporous organosilicas (PMO) are prepared by the surfactant-templated
condensation of bridged organosilsesquioxane monomers. By controlling the nature of the …

The synthesis of chiral periodic organosilica materials with ultrasmall mesopores.

X Wu, T Blackburn, JD Webb… - … (International ed. in …, 2011 - europepmc.org
Helical organosilica materials were synthesized for the first time using a novel binaphthyl-
based chiral co-monomer in less than 1 hour. The incorporation of a chiral co-monomer in …

Synthesis and Characterization of Chiral Benzylic Ether‐Bridged Periodic Mesoporous Organosilicas

J Morell, S Chatterjee, PJ Klar… - … A European Journal, 2008 - Wiley Online Library
The first synthesis of a chiral periodic mesoporous organosilica (PMO) carrying benzylic
ether bridging groups is reported. By hydrolysis and condensation of the new designed …

Chiral hybrid mesoporous silicas: Assembly of uniform hollow nanospheres and helical nanotubes with tunable diameters

X Wu, CM Crudden - Chemistry of Materials, 2012 - ACS Publications
Uniform helical silica nanotubes and hollow silica nanostructures with adjustable diameters
have been prepared through the self-assembly of sodium dodecyl sulfate (SDS) as the …

Control of morphology and helicity of chiral mesoporous silica

H Jin, Z Liu, T Ohsuna, O Terasaki, Y Inoue… - Advanced …, 2006 - Wiley Online Library
Chiral ordered mesoporous silica has been synthesized by using a chiral surfactant (N‐
myristoyl‐L‐alanine sodium salt) as a template, 3‐aminopropyltriethoxysilane as a co …

Chiral norbornane-bridged periodic mesoporous organosilicas

TY Zhuang, JY Shi, BC Ma, W Wang - Journal of Materials Chemistry, 2010 - pubs.rsc.org
A highly-ordered chiral norbornane-bridged periodic mesoporous organosilica (PMO) was
synthesized via self-condensation of chiral precursor (1R, 2S, 4R, 5S)-exo, exo-2, 5-bis …