Comparative Investigation of the Hydrolysis of Charge‐Shifting Polymers Derived from an Azlactone‐Based Polymer

A Fortenberry, SA Mohammad… - Macromolecular rapid …, 2022 - Wiley Online Library
Abstract Poly 2‐vinyl‐4, 4‐dimethylazlactone (PVDMA) has received much attention as a
“reactive platform” to prepare charge‐shifting polycations via post‐polymerization …

Synthesis and Properties of Charge-Shifting Polycations: Poly[3-aminopropylmethacrylamide-co-2-(dimethylamino)ethyl acrylate]

S Ros, NAD Burke, HDH Stöver - Macromolecules, 2015 - ACS Publications
Charge-shifting copolymers of N-(3-aminopropyl) methacrylamide (APM) and 2-
(dimethylamino) ethyl acrylate (DMAEA) were prepared and investigated as potential …

Precise Control of Molecular Weight Characteristics of Charge‐Shifting Poly(2‐(N,N‐Dimethylamino)Ethylacrylate) Synthesized by Reversible Addition …

R Sivkova, R Konefal, L Kostka, R Laga… - Macromolecular …, 2024 - Wiley Online Library
Abstract Poly (2‐(N, N‐dimethylamino) ethyl acrylate)(PDMAEA) is a promising charge‐
shifting polycation with the capacity to form a range of morphologically distinct …

Charge-shifting polycations with tunable rates of hydrolysis: effect of backbone substituents on poly [2-(dimethylamino) ethyl acrylates]

S Ros, RM Kleinberger, NAD Burke, NAA Rossi… - …, 2018 - ACS Publications
While polycations based on 2-(dimethylamino) ethyl methacrylate and 2-(dimethylamino)
ethyl acrylate are used in applications ranging from biomaterials to wastewater treatment …

A Mechanistic Study of the Hydrolysis of Poly[N,N-(dimethylamino)ethyl acrylates] as Charge-Shifting Polycations

S Ros, J Wang, NAD Burke, HDH Stover - Macromolecules, 2020 - ACS Publications
Polycations are used extensively in applications ranging from enhanced oil recovery to
biomaterials. Poly [N, N-(dimethylamino) ethyl acrylate](PDMAEA) has attracted interest for …

Charge‐conversional poly (amino acid) s derivatives as a drug delivery carrier in response to the tumor environment

SR Yoon, HM Yang, CW Park, S Lim… - … Research Part A, 2012 - Wiley Online Library
A charge‐converting and pH‐dependent nanocarrier was achieved by conjugating 2, 3‐
dimethylmaleic anhydride (DMMA) to the amino group of an octadecyl grafted poly (2 …

Azlactone-based copolymers by redox-initiated MADIX polymerization at room temperature in ethanol

F François, G Gody, J Wilson, L Fontaine… - Polymer …, 2024 - pubs.rsc.org
Macromolecular design via the interchange of xanthate (MADIX) polymerization of 2-vinyl-4,
4-dimethylazlactone (VDM) used as comonomer is reported. Rhodixan® A1 was employed …

Precision polyelectrolytes

S Srichan, L Oswald, M Zamfir, JF Lutz - Chemical Communications, 2012 - pubs.rsc.org
Charged macromolecules with controlled microstructures were prepared. Well-defined non-
ionic precursors were first synthesized by sequence-controlled radical polymerization of tert …

Reactive Polyanions Based on Poly(4,4-dimethyl-2-vinyl-2-oxazoline-5-one-co-methacrylic acid)

CM Gardner, HDH Stöver - Macromolecules, 2011 - ACS Publications
The formation of reactive polyanions by semibatch copolymerization of 4, 4-dimethyl-2-vinyl-
2-oxazoline-5-one (VDMA) and methacrylic acid (MAA) by both free radical and …

Synthesis and characterization of backbone degradable azlactone-functionalized polymers

MCD Carter, J Jennings, V Appadoo, DM Lynn - Macromolecules, 2016 - ACS Publications
We report the design of reactive and degradable copolymers that contain both azlactone
side chain functionality and hydrolyzable backbone ester groups. Copolymerization of the …