Protection of inorganic semiconductors for sustained, efficient photoelectrochemical water oxidation

MF Lichterman, K Sun, S Hu, X Zhou, MT McDowell… - Catalysis Today, 2016 - Elsevier
Small-band-gap (E g< 2 eV) semiconductors must be stabilized for use in integrated devices
that convert solar energy into the bonding energy of a reduced fuel, specifically H 2 (g) or a …

Stable solar-driven oxidation of water by semiconducting photoanodes protected by transparent catalytic nickel oxide films

K Sun, FH Saadi, MF Lichterman… - Proceedings of the …, 2015 - National Acad Sciences
Reactively sputtered nickel oxide (NiOx) films provide transparent, antireflective, electrically
conductive, chemically stable coatings that also are highly active electrocatalysts for the …

Stable Solar-Driven Water Oxidation to O2(g) by Ni-Oxide-Coated Silicon Photoanodes

K Sun, MT McDowell, AC Nielander, S Hu… - The journal of …, 2015 - ACS Publications
Semiconductors with small band gaps (< 2 eV) must be stabilized against corrosion or
passivation in aqueous electrolytes before such materials can be used as photoelectrodes …

p-Type transparent conducting oxide/n-type semiconductor heterojunctions for efficient and stable solar water oxidation

L Chen, J Yang, S Klaus, LJ Lee… - Journal of the …, 2015 - ACS Publications
Achieving stable operation of photoanodes used as components of solar water splitting
devices is critical to realizing the promise of this renewable energy technology. It is shown …

Stabilization of n-cadmium telluride photoanodes for water oxidation to O 2 (g) in aqueous alkaline electrolytes using amorphous TiO 2 films formed by atomic-layer …

MF Lichterman, AI Carim, MT McDowell, S Hu… - Energy & …, 2014 - pubs.rsc.org
Although II–VI semiconductors such as CdS, CdTe, CdSe, ZnTe, and alloys thereof can have
nearly ideal band gaps and band-edge positions for the production of solar fuels, II–VI …

Thin-film materials for the protection of semiconducting photoelectrodes in solar-fuel generators

S Hu, NS Lewis, JW Ager, J Yang… - The Journal of …, 2015 - ACS Publications
The electrochemical instability of semiconductors in aqueous electrolytes has impeded the
development of robust sunlight-driven water-splitting systems. We review the use of …

Interfacial engineering of metal-insulator-semiconductor junctions for efficient and stable photoelectrochemical water oxidation

IA Digdaya, GWP Adhyaksa, BJ Trześniewski… - Nature …, 2017 - nature.com
Solar-assisted water splitting can potentially provide an efficient route for large-scale
renewable energy conversion and storage. It is essential for such a system to provide a …

Molecular water-oxidation catalysts for photoelectrochemical cells

R Brimblecombe, GC Dismukes, GF Swiegers… - Dalton …, 2009 - pubs.rsc.org
Photoelectrochemical cells that efficiently split water into oxygen and hydrogen,“the fuel of
the future”, need to combine robust water oxidation catalysts at the anode (2H2O→ O2+ …

An electrodeposited inhomogeneous metal–insulator–semiconductor junction for efficient photoelectrochemical water oxidation

JC Hill, AT Landers, JA Switzer - Nature materials, 2015 - nature.com
The photoelectrochemical splitting of water into hydrogen and oxygen requires a
semiconductor to absorb light and generate electron–hole pairs, and a catalyst to enhance …

Solar-driven photoelectrochemical water oxidation over an n-type lead–titanium oxyfluoride anode

N Hirayama, H Nakata, H Wakayama… - Journal of the …, 2019 - ACS Publications
Mixed-anion compounds (eg, oxynitrides and oxysulfides) are potential candidates as
photoanodes for visible-light water oxidation, but most of them suffer from oxidative …