Reversible twisting during helical hippuric acid crystal growth

AG Shtukenberg, J Freudenthal… - Journal of the American …, 2010 - ACS Publications
Crystals grow in the mind's eye by the addition of small units to a monolith each part of which
is in fixed translational relation to every other part. Here, it is shown that growth can induce …

Mechanics of twisted hippuric acid crystals untwisting as they grow

AG Shtukenberg, A Gujral, E Rosseeva, X Cui… - …, 2015 - pubs.rsc.org
Spontaneous twisting of single crystals is a common growth induced deformation. But as
twisted crystals thicken they can untwist, restoring a straight form. The mechanics of this …

Crystals of benzamide, the first polymorphous molecular compound, are helicoidal

AG Shtukenberg, R Drori, EV Sturm… - Angewandte …, 2020 - Wiley Online Library
The growth of spontaneously twisted crystals is a common but poorly understood
phenomenon. An analysis of the formation of twisted crystals of a metastable benzamide …

Hydrogen-bond directed cocrystallization as a tool for designing acentric organic solids

MC Etter, GM Frankenbach - Chemistry of materials, 1989 - ACS Publications
Figure 1. Photograph of a typical crystal of I (approximately 0.5 cm along the longest edge).
On the right is a schematic diagram of the crystal showing Miller index assignments of the …

Growth actuated bending and twisting of single crystals

AG Shtukenberg, YO Punin, A Gujral… - Angewandte Chemie …, 2014 - Wiley Online Library
Crystals of a variety of substances including elements, minerals, simple salts, organic
molecular crystals, and high polymers forgo long‐range translational order by twisting and …

Crystal engineering of hand-twisted helical crystals

S Saha, GR Desiraju - Journal of the American Chemical Society, 2017 - ACS Publications
A strategy is outlined for the design of hand-twisted helical crystals. The starting point in the
exercise is the one-dimensional (1D) plastic crystal, 1, 4-dibromobenzene, which is then …

Emergence of helical morphologies with crystals: twisted growth under diffusion-limited conditions and chirality control with molecular recognition

H Imai, Y Oaki - CrystEngComm, 2010 - pubs.rsc.org
Twisted crystals are widely observed in natural minerals and artificial materials. However,
the formation mechanism for most of the helical morphologies is quite complicated and, thus …

Stereochemistry and twisted crystals

CE Killalea, DB Amabilino - Israel Journal of Chemistry, 2021 - Wiley Online Library
This review article discusses a link between stereochemistry and structural and
morphological chirality. We present the remarkably frequent, but less often reported, growth …

Direct observation of transient Ostwald crystallization ordering from racemic serine solutions

VJ Hall, GJ Simpson - Journal of the American Chemical Society, 2010 - ACS Publications
The Ostwald rule of stages describes the conjectured transitioning through metastable
polymorphic crystal structures during crystallization. Direct observation of the Ostwald rule of …

Common occurrence of twisted molecular crystal morphologies from the melt

AG Shtukenberg, X Zhu, Y Yang… - Crystal Growth & Design, 2020 - ACS Publications
Two books that describe the forms of thin films of many molecular crystals grown from the
melt in polarized light,“Gedrillte” Kristalle (1929) by Ferdinand Bernauer and …