Non-catalytic approach to the synthesis of partially reduced 'S'shaped dioxathia-and oxadithiahelicenes through base induced inter-and intramolecular C–C bond …

HK Maurya, VK Tandon, B Kumar, A Kumar… - Organic & …, 2012 - pubs.rsc.org
An efficient and convenient route for the construction of helical 'S'shaped dioxathia-and
oxadithiahelicenes with oxygen and sulfur atoms located in the middle of the outer helix has …

Partially reduced thiochromene based oxathiahelicenes: crystallographic, computational and Hirschfeld surface analyses

A Kumar, V Hüch, VJ Ram - CrystEngComm, 2013 - pubs.rsc.org
An efficient and concise route for the construction of thiochromene based oxahelicenes in
which heteroatoms are located on the outer helix through base-induced ring transformation …

Metal-free synthesis of nitrile based partially reduced thia-and oxa-thia [5] helicenes: conformation and dynamics

R Pratap, A Kumar, R Pick, V Hüch, VJ Ram - RSC advances, 2012 - pubs.rsc.org
An expeditious, metal free, simple and convenient synthesis of partially reduced thia [5]
helicenes and oxa-thia [5] helicenes, appended with nitrile and amino functionalities such as …

Regio-defined amino [5] oxa-and thiahelicenes: a dramatic impact of the nature of the heteroatom on the helical shape and racemization barriers

G Pieters, A Gaucher, S Marque, F Maurel… - The Journal of …, 2010 - ACS Publications
The present approach to heterohelicenes provides original [5] oxa-and thiahelicenes, where
both oxygen and sulfur atoms are located at the end of the inner helix. Quantum chemical …

Synthesis of All Thiophene-Based [7] Helicenes and Trithienothiepines with Isomeric Location of Sulfur Atoms Based on Intramolecular Selectivity of Deprotonation

J Wang, G Wang, C Li, Y Dong, Z Ma… - The Journal of Organic …, 2021 - ACS Publications
Three unsymmetric thiophene-based [7] helicenes, namely, endo-exo-UH-1, endo-top-UH-2,
and exo-top-UH-3, with different isomeric locations of sulfur atoms in two terminal thiophene …

[引用][C] The Synthesis of Octyl-Substituted Hexathia [7] heterohelicene Based on dithieno [2, 3-b: 3', 2'-d] thiophene via Irradiation

Z Wang, J Shi, C Li, D Zhao, Z Wang… - Letters in Organic …, 2010 - ingentaconnect.com
With 2-octyl dithieno [2, 3-b: 3', 2'-d] thiophene as raw material, three steps including
formylation, McMurry reaction and photocylization were employed to generate dioctyl …

Non-photochemical route to chiral disubstituted [7] thiaheterohelicenes via biaryl-and carbonyl-coupling reactions

K Tanaka, H Suzuki, H Osuga - The Journal of Organic Chemistry, 1997 - ACS Publications
Non-photochemical syntheses of optically active dimethyl [7] thiaheterohelicenes (P)-(+)-14
and (M)-(−)-14 are described. The key transformations in the syntheses are the metal …

[PDF][PDF] Novel Synthesis of Thioalkoxy-Substituted Oxa [9] helicenes by the Reaction of Helical Quinones with Thiols

M Salim, T Kimura, M Karikomi - Heterocycles, 2013 - triggered.edina.clockss.org
The reaction of helical quinone with thiols in the presence of acid such as HCl, para-toluene
sulfonic acid (pTSA), or Yb (OTf) 3· 3H2O to form resulted in the formation of thioalkoxy …

Diversified Syntheses of Tetrathia [7] helicenes by Metal‐Catalyzed Cross‐Coupling Reactions

V Pelliccioli, D Dova, C Baldoli, C Graiff… - European Journal of …, 2021 - Wiley Online Library
Efficient and versatile synthetic routes to functionalized tetrathia [7] helicenes (7‐THs) are
described. The key intermediates of these methodologies are 2‐bromo‐3, 3′‐bibenzo [1, 2 …

Partially Hydrogenated 7‐Oxa [5] helicenes and [5] Helicenes: Synthesis, Structures, and Dynamics

A Goel, D Verma, R Pratap, G Taneja, Y Hemberger… - 2011 - Wiley Online Library
An efficient and convenient synthesis of partially hydrogenated functionalized [5] helicenes
and oxa [5] helicenes, such as (1, 2, 5, 6‐tetrahydro‐3‐oxadibenzo [c, g] phenanthren‐4 …