Pd-catalyzed amination of base-sensitive five-membered heteroaryl halides with aliphatic amines

EC Reichert, K Feng, AC Sather… - Journal of the American …, 2023 - ACS Publications
We report a versatile and functional-group-tolerant method for the Pd-catalyzed C–N cross-
coupling of five-membered heteroaryl halides with primary and secondary amines, an …

Palladium-metalated porous organic polymers as recyclable catalysts for the chemioselective synthesis of thiazoles from thiobenzamides and isonitriles

W Tong, WH Li, Y He, ZY Mo, HT Tang, HS Wang… - Organic …, 2018 - ACS Publications
Two types of thiazole derivatives are synthesized through a multistep cascade sequence
with Pd-metalated phosphorus-doped porous organic polymers (POPs) as heterogeneous …

Pd-Catalyzed Asymmetric Oxidative C–H/C–H Cross-Coupling Reaction between Ferrocenes and Azoles

F Cao, Y Wang, P Feng, J Hu, Y Yang… - The Journal of Organic …, 2023 - ACS Publications
The asymmetric C–H bond functionalization reaction is one of the most efficient and
straightforward methods for the synthesis of optically active molecules. Herein, our work …

Design and synthesis of disubstituted and trisubstituted thiazoles as multifunctional fluorophores with large Stokes shifts

PO Suntsova, AK Eltyshev, TA Pospelova… - Dyes and …, 2019 - Elsevier
A series of fluorophores based on a thiazole core have been synthesized and shown to be
very sensitive to both structural changes and the microenvironment. Simple modifications of …

NIXANTPHOS: a highly active ligand for palladium catalyzed Buchwald–Hartwig amination of unactivated aryl chlorides

J Mao, J Zhang, S Zhang, PJ Walsh - Dalton Transactions, 2018 - pubs.rsc.org
Xantphos is one of the two most common ligands used in palladium catalyzed Buchwald–
Hartwig amination reactions, because of its broad scope and high probability of success. It …

5‐N, N‐Diarylaminothiazoles with Electron‐Accepting Groups: Synthesis, Photophysical Properties, and Their Application for the Detection of Hydrazine Hydrate

T Murai, N Tanaka, K Takekoshi… - European Journal of …, 2024 - Wiley Online Library
N, N‐diarylaminothiazoles containing cyano and nitro groups were synthesized using the Pd‐
catalyzed Buchwald‐Hartwig amination reaction with good yields. The cyano group in the …

Pd‐Catalyzed Decarbonylative C− H Coupling of Azoles and Aromatic Esters

K Matsushita, R Takise, T Hisada… - Chemistry–An Asian …, 2018 - Wiley Online Library
Abstract A decarbonylative C− H coupling of azoles and aromatic esters by palladium
catalysis is described. Our previously reported Ni‐catalyzed C− H coupling of azoles and …

Asymmetric Dual‐State Emitters Featuring Thiazole Acceptors

JL Belmonte‐Vázquez… - European Journal of …, 2022 - Wiley Online Library
This work describes a new approach to construct highly conjugated molecules with
asymmetric donor‐acceptor‐donor'architectures (D− A− D'). Five new emissive compounds …

3-Aryl-2-(thiazol-2-yl) acrylonitriles assembled with aryl/hetaryl rings: Design of the optical properties and application prospects

AK Eltyshev, TH Dzhumaniyazov, PO Suntsova… - Dyes and …, 2021 - Elsevier
New fluorescent thiazoles were designed and synthesized based on a 3-aryl-2-(thiazol-2-yl)
acrylonitrile core. Three synthetic approaches were developed to introduce specific …

Donor–Acceptor π-Conjugated Enamines: Functional Group-Compatible Synthesis from Amides and Their Photoabsorption and Photoluminescence Properties

A Tahara, I Kitahara, D Sakata… - The Journal of …, 2019 - ACS Publications
High functional group compatibility of iridium-catalyzed synthesis of enamines from amides
and 1, 1, 3, 3-tetramethyldisiloxane (TMDS) realized facile access of a series of donor (D)− π …