Doping by design: enhanced thermoelectric performance of GeSe alloys through metavalent bonding

Y Yu, C Zhou, T Ghosh, CF Schön, Y Zhou… - Advanced …, 2023 - Wiley Online Library
Doping is usually the first step to tailor thermoelectrics. It enables precise control of the
charge‐carrier concentration and concomitant transport properties. Doping should also turn …

Intrinsically Low Lattice Thermal Conductivity and Anisotropic Thermoelectric Performance in In‐doped GeSb2Te4 Single Crystals

P Chen, H Wu, B Zhang, Z Zhou… - Advanced Functional …, 2023 - Wiley Online Library
Abstract Layer‐structured GeSb2Te4 is a promising thermoelectric candidate, while its
anisotropy of thermal and electrical transport properties is still not clear. In this study, Ge1 …

Atom Probe Tomography Advances Chalcogenide Phase‐Change and Thermoelectric Materials

Y Yu, O Cojocaru-Mirédin, M Wuttig - physica status solidi (a), 2023 - Wiley Online Library
Main‐group chalcogenides show outstanding performance for phase‐change data storage
and thermoelectric energy conversion applications. A common denominator for these …

In situ design of high‐performance dual‐phase GeSe thermoelectrics by tailoring chemical bonds

L Hu, B Duan, T Lyu, N Lin, C Zhang… - Advanced Functional …, 2023 - Wiley Online Library
Composite engineering favors high thermoelectric performance by tuning the carrier and
phonon transport. Herein, orthorhombic and rhombohedral dual‐phase GeSe are designed …

[PDF][PDF] Two-step phase manipulation by tailoring chemical bonds results in high-performance GeSe thermoelectrics

W Yao, Y Zhang, T Lyu, W Huang, N Huang, X Li… - The Innovation, 2023 - cell.com
In thermoelectrics, phase engineering serves a crucial function in determining the power
factor by affecting the band degeneracy. However, for low-symmetry compounds, the …

[HTML][HTML] Approaching high thermoelectric performance in p-type Cu3SbS4-based materials by rational electronic and nano/microstructural engineering

J Yang, XL Shi, Q Yang, W Shen, M Li, Z Zhang… - Chemical Engineering …, 2023 - Elsevier
Due to the eco-friendly and earth-abundant features, p-type Cu 3 SbS 4-based sulfides have
shown great potential as cost-effective thermoelectric materials for practical applications in …

The Role of Cation Vacancies in GeSe: Stabilizing High‐Symmetric Phase Structure and Enhancing Thermoelectric Performance

B Duan, Y Zhang, Q Yang, Y Li, J Cheng… - Advanced Energy …, 2022 - Wiley Online Library
Enhancing crystal symmetry is perceived as the most efficacious strategy to improve the
thermoelectric performance of GeSe. Although multicomponent alloying is commonly …

Achieving Superior Thermoelectric Performance in Ge4Se3Te via Symmetry Manipulation with I–V–VI2 Alloying

M Guo, HH Cui, W Guo, Z Chen, H Ming… - Advanced Functional …, 2024 - Wiley Online Library
Although orthorhombic GeSe is predicted to have an ultrahigh figure of merit, ZT≈ 2.5, up to
now, the highest experimental value is≈ 0.2 due to the low carrier concentration (nH≈ 1018 …

Manipulation of metavalent bonding to stabilize metastable phase: A strategy for enhancing zT in GeSe

Y Huang, T Lyu, M Zeng, M Wang, Y Yu… - Interdisciplinary …, 2024 - Wiley Online Library
Exploration of metastable phases holds profound implications for functional materials.
Herein, we engineer the metastable phase to enhance the thermoelectric performance of …

Leveraging crystal symmetry for thermoelectric performance optimization in cubic GeSe

YG Li, YQ Liu, MR Wang, WQ Yao, XH Luo, T Lyu… - Rare Metals, 2024 - Springer
In thermoelectrics, the manipulation of crystal symmetry is instrumental in optimizing the
electrical and thermal transport parameters. Within this context, the present study explored …