Emerging electrolytes with fluorinated solvents for rechargeable lithium-based batteries

Y Wang, Z Li, Y Hou, Z Hao, Q Zhang, Y Ni… - Chemical Society …, 2023 - pubs.rsc.org
Electrolytes that can ensure the movement of ions and regulate interfacial chemistries for
fast mass and charge transfer are essential in many types of electrochemical energy storage …

Contemporary synthetic strategies in organofluorine chemistry

R Britton, V Gouverneur, JH Lin, M Meanwell… - Nature Reviews …, 2021 - nature.com
Fluorinated molecules have a wide range of applications and are used as medicines,
agrochemicals and refrigerants and in smartphone liquid crystal displays, photovoltaic solar …

Carbon–Carbon Bond Cleavage for Late-Stage Functionalization

YF Liang, M Bilal, LY Tang, TZ Wang, YQ Guan… - Chemical …, 2023 - ACS Publications
Late-stage functionalization (LSF) introduces functional group or structural modification at
the final stage of the synthesis of natural products, drugs, and complex compounds. It is …

Structure and nanostructure in ionic liquids

R Hayes, GG Warr, R Atkin - Chemical reviews, 2015 - ACS Publications
Much of chemistry is concerned with the study of reactions and processes in solution, that is,
where liquids are used as solvents. 2, 3 The solvent is the (excess) liquid phase in which …

Buchwald-Hartwig reaction: an overview

MM Heravi, Z Kheilkordi, V Zadsirjan, M Heydari… - Journal of …, 2018 - Elsevier
Pd-catalyzed amination reaction of aryl halides has attracted much attention in recent years.
This review underscores selected important recent developments in the catalysis of one of …

Carbon trifluoromethylation reactions of hydrocarbon derivatives and heteroarenes

C Alonso, E Martinez de Marigorta, G Rubiales… - Chemical …, 2015 - ACS Publications
Fluorine has emerged as a “magic element” in medicinal chemistry, crop, and materials
science. 1 Although fluorine is the most abundant halogen in the earth's crust, it is contained …

Good partnership between sulfur and fluorine: sulfur-based fluorination and fluoroalkylation reagents for organic synthesis

C Ni, M Hu, J Hu - Chemical Reviews, 2015 - ACS Publications
Fluorine, often called as “a small atom with a big ego”, 1 lies in the second row and the 17th
column in the periodic table of the chemical elements. This unique position in the periodic …

Difluoromethylation reactions of organic compounds

DE Yerien, S Barata‐Vallejo… - Chemistry–A European …, 2017 - Wiley Online Library
The relevance of the‐CF2H moiety has attracted considerable attention from organic
synthetic and medicinal chemistry communities, because this group can act as a more …

Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions

XH Xu, K Matsuzaki, N Shibata - Chemical reviews, 2015 - ACS Publications
1. INTRODUCTION Fluorine is the most abundant halogen in the Earth, s crust. 1 However,
only a dozen fluorinated organic compounds have been identified in nature. 2 Most of the …

Functionalization of fluorinated molecules by transition-metal-mediated C–F bond activation to access fluorinated building blocks

T Ahrens, J Kohlmann, M Ahrens, T Braun - Chemical Reviews, 2015 - ACS Publications
Fluorinated organic compounds increasingly gain importance in numerous areas of
chemistry and everyday life. Building blocks which contain fluorinated entities are of high …