Industrial synthesis of reactive silicones: Reaction mechanisms and processes

T Köhler, A Gutacker, E Mejía - Organic Chemistry Frontiers, 2020 - pubs.rsc.org
Silicones and silicone rubbers are ubiquitous in our daily lives, being used in a broad range
of applications ranging from consumer products and adhesives to medicinal and electronic …

Anhydrous polymeric proton conductors based on imidazole functionalized polysiloxane

G Scharfenberger, WH Meyer, G Wegner… - Fuel Cells, 2006 - Wiley Online Library
Intrinsically proton conducting polymers with imidazole as proton solvent tethered to a
polysiloxane backbone via a flexible spacer have been synthesized. Apart from the standard …

Fast synthesis of high molecular weights polydiethylsiloxanes and random poly (dimethylsiloxane-co-diethylsiloxane) copolysiloxanes via cyclic trimeric phosphazene …

Z Liu, J Shi, N Zhao, Z Li - European Polymer Journal, 2022 - Elsevier
Polysiloxanes containing diethylsiloxane units with unique low temperature flexibility have
been widely applied under extreme conditions in many fields. However, the synthesis of …

Mechanical properties and swelling behavior of end-linked poly (diethylsiloxane) networks

RC Hedden, H Saxena, C Cohen - Macromolecules, 2000 - ACS Publications
Linear α, ω-vinyl-terminated poly (diethylsiloxane)(PDES) chains were synthesized and
fractionated to obtain melts of low polydispersity. The fractionated samples were …

Preparation of Monotrimethoxylsilylethyl-Terminated Polysiloxane Fluids and Their Application in Thermal Interface Materials

Y Liu, X Long, Y Wang, C Wu, Z Qu, Z Pei, C Shi… - Polymers, 2023 - mdpi.com
In this study, α-Trimethylsilylmethyl-ω-dimethylsilyl-terminated polydimethylsiloxane,
polydiethylsiloxane and poly [2, 2, 2-trifluoropropyl (methyl) siloxane] are synthesized using …

Effects of molecular structure on segment orientation in siloxane elastomers. 1. NMR measurements from compressed samples

RC Hedden, E McCaskey, C Cohen… - Macromolecules, 2001 - ACS Publications
2H NMR spectral data are reported for two types of compressed, deuterium-labeled siloxane
elastomers: 2H-labeled poly (diethylsiloxane)(PDES) networks and 2H-labeled poly …

Conformational Behavior of Guest Chains in Uniaxially Stretched Poly(diethylsiloxane) Elastomers:  2H NMR and SANS

A Batra, RC Hedden, P Schofield, A Barnes… - …, 2003 - ACS Publications
2H nuclear magnetic resonance (NMR) and small angle neutron scattering (SANS) data are
reported for deuterated guest chains of polydiethysiloxane (PDES) in end-linked PDES …

23 Inorganic and organometallic polymers

ML Turner - Annual Reports Section" A"(Inorganic Chemistry), 2001 - pubs.rsc.org
Macromolecules containing main group or d-block elements in their backbone continue to
attract considerable attention because of the synthetic challenges involved in their …

Synthesis of silicone magnetic fluids for use in eye surgery

M Rutnakornpituk - 2002 - search.proquest.com
Stable suspensions of superparamagnetic cobalt nanoparticles have been prepared in poly
(dimethysiloxane)(PDMS) carrier fluids in the presence of poly [dimethylsiloxane-b-(3 …

Rheological studies on mesomorphic poly (diethylsiloxane) melts

H Saxena, RC Hedden, C Cohen - Journal of Rheology, 2002 - pubs.aip.org
Rheological data are reported for five fractions of poly (diethylsiloxane)(PDES) with molar
masses of PDES ranging from 45 to 200 kg/mol. At room temperature, the samples exhibit a …