Visible-light induced dearomatization reactions

YZ Cheng, Z Feng, X Zhang, SL You - Chemical Society Reviews, 2022 - pubs.rsc.org
Dearomatization reactions provide rapid access to structurally complex three-dimensional
molecules from simple aromatic compounds. Plenty of reports have demonstrated their …

Recent advances in the electrochemical generation of 1, 3-dicarbonyl radicals from C–H bonds

Q Wan, Z Zhang, ZW Hou, L Wang - Organic Chemistry Frontiers, 2023 - pubs.rsc.org
Electrochemistry, which employs electrons as reagents and avoids the use of traditional
redox reagents, becomes a powerful tool in oxidative dehydrogenation cross-coupling …

Recent Advances in the Construction of Spiro Compounds via Radical Dearomatization

WC Yang, MM Zhang, JG Feng - Advanced Synthesis & …, 2020 - Wiley Online Library
The field in dearomatization of aromatic compounds for the construction of spirocycle
compounds has been developed rapidly over the last two decades and it provides …

Electrochemical Dearomatizing Spirocyclization of Alkynes with D imethyl 2-Benzylmalonate s to Spiro [4.5] deca-trienones

L Li, ZW Hou, P Li, L Wang - The Journal of Organic Chemistry, 2022 - ACS Publications
An electrochemical dearomatizing spirocyclization of alkynes with dimethyl 2-
benzylmalonates for the preparation of spiro [4.5] deca-trienones has been developed. This …

Visible‐light‐induced dearomatizations

M Okumura, D Sarlah - European journal of organic chemistry, 2020 - Wiley Online Library
The dearomatization of aromatic compounds is an important synthetic strategy used in
accessing complex three‐dimensional structures from simple aromatic precursors. This …

Photocatalytic functionalizations of alkynes

N Chalotra, J Kumar, T Naqvi, BA Shah - Chemical Communications, 2021 - pubs.rsc.org
Visible light mediated functionalizations have significantly expanded the scope of alkynes by
unraveling new mechanistic pathways and enabling their transformation to diverse structural …

Dearomatization of biaryls through polarity mismatched radical spirocyclization

CR Azpilcueta‐Nicolas, D Meng… - Angewandte Chemie …, 2023 - Wiley Online Library
Dearomatization reactions involving radical cyclizations can facilitate the synthesis of
complex polycyclic systems that find applications in medicinal chemistry and natural product …

Visible-light-induced dearomatization via [2+ 2] cycloaddition or 1, 5-hydrogen atom transfer: divergent reaction pathways of transient diradicals

M Zhu, X Zhang, C Zheng, SL You - ACS Catalysis, 2020 - ACS Publications
Visible-light-induced dearomatization reaction via energy-transfer mechanism is an
emerging strategy for the synthesis of highly strained polycyclic molecules. Transient, high …

Dearomative Photocatalytic Construction of Bridged 1, 3‐Diazepanes

JA Leitch, T Rogova, F Duarte… - Angewandte Chemie, 2020 - Wiley Online Library
The construction of diverse sp3‐rich skeletal ring systems is of importance to drug discovery
programmes and natural product synthesis. Herein, we report the photocatalytic construction …

Visible light promoted difunctionalization reactions of alkynes

X Ren, Z Lu - Chinese Journal of Catalysis, 2019 - Elsevier
Visible light promoted difunctionalization of alkynes is reviewed. The difunctionalization
reaction is achieved by different reagents. Radicals such as carbon (sp 3), carbon (sp 2) …