Q Wan, Z Zhang, ZW Hou, L Wang - Organic Chemistry Frontiers, 2023 - pubs.rsc.org
Electrochemistry, which employs electrons as reagents and avoids the use of traditional redox reagents, becomes a powerful tool in oxidative dehydrogenation cross-coupling …
The field in dearomatization of aromatic compounds for the construction of spirocycle compounds has been developed rapidly over the last two decades and it provides …
L Li, ZW Hou, P Li, L Wang - The Journal of Organic Chemistry, 2022 - ACS Publications
An electrochemical dearomatizing spirocyclization of alkynes with dimethyl 2- benzylmalonates for the preparation of spiro [4.5] deca-trienones has been developed. This …
M Okumura, D Sarlah - European journal of organic chemistry, 2020 - Wiley Online Library
The dearomatization of aromatic compounds is an important synthetic strategy used in accessing complex three‐dimensional structures from simple aromatic precursors. This …
N Chalotra, J Kumar, T Naqvi, BA Shah - Chemical Communications, 2021 - pubs.rsc.org
Visible light mediated functionalizations have significantly expanded the scope of alkynes by unraveling new mechanistic pathways and enabling their transformation to diverse structural …
Dearomatization reactions involving radical cyclizations can facilitate the synthesis of complex polycyclic systems that find applications in medicinal chemistry and natural product …
M Zhu, X Zhang, C Zheng, SL You - ACS Catalysis, 2020 - ACS Publications
Visible-light-induced dearomatization reaction via energy-transfer mechanism is an emerging strategy for the synthesis of highly strained polycyclic molecules. Transient, high …
JA Leitch, T Rogova, F Duarte… - Angewandte Chemie, 2020 - Wiley Online Library
The construction of diverse sp3‐rich skeletal ring systems is of importance to drug discovery programmes and natural product synthesis. Herein, we report the photocatalytic construction …
X Ren, Z Lu - Chinese Journal of Catalysis, 2019 - Elsevier
Visible light promoted difunctionalization of alkynes is reviewed. The difunctionalization reaction is achieved by different reagents. Radicals such as carbon (sp 3), carbon (sp 2) …