Renaissance of Strong Metal–Support Interactions

M Xu, M Peng, H Tang, W Zhou, B Qiao… - Journal of the American …, 2024 - ACS Publications
Strong metal–support interactions (SMSIs) have emerged as a significant and cutting-edge
area of research in heterogeneous catalysis. They play crucial roles in modifying the …

Restructuring of titanium oxide overlayers over nickel nanoparticles during catalysis

M Monai, K Jenkinson, AEM Melcherts, JN Louwen… - Science, 2023 - science.org
Reducible supports can affect the performance of metal catalysts by the formation of
suboxide overlayers upon reduction, a process referred to as the strong metal–support …

Nonclassical Strong Metal–Support Interactions for Enhanced Catalysis

Y Sun, Z Yang, S Dai - The Journal of Physical Chemistry Letters, 2023 - ACS Publications
Strong metal–support interaction (SMSI), which encompasses reversible encapsulation and
de-encapsulation and modulation of surface adsorption properties, imposes great impacts …

Direct conversion of CO and H2O to hydrocarbons at atmospheric pressure using a TiO2−x/Ni photothermal catalyst

X Qin, M Xu, J Guan, L Feng, Y Xu, L Zheng, M Wang… - Nature Energy, 2024 - nature.com
Hydrocarbon fuels can be synthesized from CO and water via Kölbel–Engelhardt synthesis,
a thermocatalytic process in which temperatures of≥ 200° C and elevated pressures are …

Deep Insight into Characterizing the Metal–Support Interface in Heterogeneous Catalysis

J Liu, L Chen, X Liu - Acs Catalysis, 2024 - ACS Publications
Supported metal species are widely used as catalysts in heterogeneous catalysis. Apart
from the extended metal surfaces, metal–support interfaces also play a crucial role in …

Tunable Interfacial Electronic Pd–Si Interaction Boosts Catalysis via Accelerating O2 and H2O Activation

T Dong, J Ji, L Yu, P Huang, Y Li, Z Suo, B Liu, Z Hu… - JACS Au, 2023 - ACS Publications
Engineering the interfacial structure between noble metals and oxides, particularly on the
surface of non-reducible oxides, is a challenging yet promising approach to enhancing the …

Layered Double Hydroxide Derivatives for Polyolefin Upcycling

M Chu, X Wang, X Wang, P Xu, L Zhang… - Journal of the …, 2024 - ACS Publications
While Ru-catalyzed hydrogenolysis holds significant promise in converting waste polyolefins
into value-added alkane fuels, a major constraint is the high cost of noble metal catalysts. In …

Development of Mg-Modified Fe-Based Catalysts for Low-Concentration CO2 Hydrogenation to Olefins

K Liu, D Xu, H Fan, G Hou, Y Li, S Huang… - ACS Sustainable …, 2024 - ACS Publications
With mounting concerns about reducing carbon emissions, developing a catalyst that can be
used in the hydrogenation of CO2 to olefins makes sense. Considering the high cost of CO2 …

Engineering ZrO2–Ru interface to boost Fischer-Tropsch synthesis to olefins

H Yu, C Wang, X Xin, Y Wei, S Li, Y An, F Sun… - Nature …, 2024 - nature.com
Understanding the structures and reaction mechanisms of interfacial active sites in the
Fisher-Tropsch synthesis reaction is highly desirable but challenging. Herein, we show that …

BCN‐Supported CoFe Alloy Catalysts for Enhanced C─ C Coupling in Photothermocatalytic CO Hydrogenation

Q Hao, Z Li, Y Zhu, Y Shi, M Huo… - Advanced Functional …, 2024 - Wiley Online Library
The high selectivity of C─ C coupling reactions in Fischer–Tropsch synthesis (FTS) is often
limited due to the difficulty in the regulation of transition metals acting as active sites to …