Direct photocatalyzed hydrogen atom transfer (d-HAT) can be considered a method of
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …

Direct substitution of readily available alcohols is recognized as a key research area in
green chemical synthesis. Starting from simple racemic secondary alcohols, the …

Enantioconvergent catalysis has expanded asymmetric synthesis to new methodologies
able to convert racemic compounds into a single enantiomer. This review covers recent …

Borrowing hydrogen or the hydrogen autotransfer amination is a powerful approach to
create single C–N bonds, starting from stable and readily available substrates: amines and …

Finite size effect is closely correlated with heterogeneous catalytic activity and selectivity as
reducing the metal to a few nanometers, but may suffer from deficient active sites for …

Synthesis of high-value-added chemicals from biomass and/or biomass-derived platform
molecules is considered an important strategy to mitigate the global dependency on fossil …

We present an enantioconvergent access to chiral N-heterocycles directly from simple
racemic diols and primary amines, through a highly economical borrowing hydrogen …

The pyridine moiety is an important core structure for a variety of drugs, agrochemicals,
catalysts, and functional materials. Direct functionalization of C− H bonds in pyridines is a …

The crucial role of the alkoxide trap problem and the impact of the oxidation state of the
chromium center were demonstrated on the catalytic activity due to the d-wall issue. Through …

A novel porous organic polymer-supported single-site nickel catalyst has been synthesized
via the Friedel–Crafts reaction of 1, 3, 5-triphenyl benzene (TPB) with 4, 6-dichloro-2-(1H …