Cononsolvency of thermoresponsive polymers: where we are now and where we are going

S Bharadwaj, BJ Niebuur, K Nothdurft, W Richtering… - Soft Matter, 2022 - pubs.rsc.org
Cononsolvency is an intriguing phenomenon where a polymer collapses in a mixture of
good solvents. This cosolvent-induced modulation of the polymer solubility has been …

Smart polymers for soft materials: from solution processing to organic solids

D Mukherji, K Kremer - Polymers, 2023 - mdpi.com
Polymeric materials are ubiquitous in our everyday life, where they find a broad range of
uses—spanning across common household items to advanced materials for modern …

Solvation Behavior of Elastin-like Polypeptides in Divalent Metal Salt Solutions

Y Zhao, S Bharadwaj, RL Myers, HI Okur… - The Journal of …, 2023 - ACS Publications
The effects of CaCl2 and MgCl2 on the cloud point temperature of two different elastin-like
polypeptides (ELPs) were studied using a combination of cloud point measurements …

[HTML][HTML] An interplay of excluded-volume and polymer–(co) solvent attractive interactions regulates polymer collapse in mixed solvents

S Bharadwaj, D Nayar, C Dalgicdir… - The Journal of …, 2021 - pubs.aip.org
Cosolvent effects on the coil–globule transitions in aqueous polymer solutions are not well
understood, especially in the case of amphiphilic cosolvents that preferentially adsorb on the …

Structural and Dynamical Properties of Elastin-Like Peptides near Their Lower Critical Solution Temperature

TI Morozova, NA García, O Matsarskaia… - …, 2023 - ACS Publications
Elastin-like peptides (ELPs) are artificially derived intrinsically disordered proteins (IDPs)
mimicking the hydrophobic repeat unit in the protein elastin. ELPs are characterized by a …

Early-Stage Oligomerization of Prion-like Polypeptides Reveals the Molecular Mechanism of Amyloid-Disrupting Capacity by Proline Residues

TY Lin, YW Ma, MY Tsai - The Journal of Physical Chemistry B, 2023 - ACS Publications
Proline cis/trans isomerization governs protein local conformational changes via its local
mechanical rigidity. The amyloid-disrupting capacity of proline is widely acknowledged; …

Conformational Characteristics and Phase Behavior of Intrinsically Disordered Proteins─ Where Physical Chemistry Meets Biology

L Arora, S Mukhopadhyay - The Journal of Physical Chemistry B, 2022 - ACS Publications
The past two decades have witnessed a burgeoning interest in a fascinating class of
proteins that do not autonomously fold into unique, well-defined, 3D structures and exist as …

A Simple Generic Model of Elastin–Like Polypeptides with Proline Isomerization

Y Zhao, R Cortes–Huerto… - Macromolecular Rapid …, 2024 - Wiley Online Library
We derive a generic model of elastin–like polypeptides (ELP) that includes proline
isomerization (ProI). As a case study, conformational transition of a–[valine–proline–glycine …

The Effects of Proline Isomerization on the Solvation Behavior of Elastin‐Like Polypeptides in Water–Ethanol Mixtures

Y Zhao, K Kremer - Macromolecular Rapid Communications, 2022 - Wiley Online Library
Elastin‐like polypeptides (ELPs) are well‐known proline‐rich stimulus‐responsive polymers.
They have broad applications ranging from drug delivery to green chemistry. Recently, the …