Nitro–Nitrito Photoisomerization of Cationic Platinum (II) Complexes in the Solid State: Reactivity in Polymorphic Crystals and Glassy State
I Nakamura, R Sumitani, T Mochida - Crystal Growth & Design, 2021 - ACS Publications
Nitro–nitrito isomerization is a well-known photoreaction exhibited by metal complexes in
the solid state. We previously reported that the isomerization ratio in the salts of a cationic …
the solid state. We previously reported that the isomerization ratio in the salts of a cationic …
Nanooptomechanical Transduction in a Single Crystal with 100% Photoconversion
JM Cole, DJ Gosztola… - The Journal of Physical …, 2021 - ACS Publications
Materials that exhibit nanooptomechanical transduction in their single-crystal form have
prospective use in light-driven molecular machinery, nanotechnology, and quantum …
prospective use in light-driven molecular machinery, nanotechnology, and quantum …
Nitro–Nitrito Photoisomerization of Platinum(II) Complexes with Pt(NO2)42– and (FSO2)2N– Anions: Correlation between Isomerization Ratio and Reaction …
I Nakamura, Y Funasako, T Mochida - Crystal Growth & Design, 2020 - ACS Publications
Nitro–nitrito linkage isomerization is a well-known photochemical reaction of metal
complexes in the solid state. To quantitatively elucidate the influence of the crystal …
complexes in the solid state. To quantitatively elucidate the influence of the crystal …
Photo- and Thermoswitchable Half-Sandwich Nickel(II) Complex: [Ni(η5-C5H5)(IMes)(η1-NO2)]
SE Kutniewska, R Kamiński, W Buchowicz… - Inorganic …, 2019 - ACS Publications
A new photoswitchable half-sandwich nitro NiII complex with the N-heterocyclic carbene
ligand was synthesized and successfully crystallized. The compound constitutes an …
ligand was synthesized and successfully crystallized. The compound constitutes an …
[PDF][PDF] Photocrystallographic and spectroscopic studies of a model (N, N, O)-donor square-planar nickel (II) nitro complex: in search of high-conversion and stable …
SE Kutniewska, A Krowczynski, R Kaminski… - IUCrJ, 2020 - journals.iucr.org
A new, cheap, easy-to-synthesize and air-stable photoswitchable nickel (II) complex,
QTNiNO2, is reported. The metal centre in QTNiNO2 is coordinated by a nitro group and a [2 …
QTNiNO2, is reported. The metal centre in QTNiNO2 is coordinated by a nitro group and a [2 …
[HTML][HTML] Exploring the influence of polymorphism and chromophore co-ligands on linkage isomer photoswitching in [Pd (bpy4dca)(NO 2) 2]
BA Coulson, LE Hatcher - CrystEngComm, 2022 - pubs.rsc.org
The polymorphic Pd (II)–nitrite complex [Pd (bpy4dca)(NO2) 2](1)(bpy4dca= 2, 2′-
bipyridine-4, 4′-dicarboxylic acid methyl ester) is shown to undergo photoinduced nitro→ …
bipyridine-4, 4′-dicarboxylic acid methyl ester) is shown to undergo photoinduced nitro→ …
Slow 3MLCT Formation Prior to Isomerization in Ruthenium Carbene Sulfoxide Complexes
R Thapa Magar, DJ Breen, BR Schrage… - Inorganic …, 2021 - ACS Publications
A series of photochromic complexes with general formulas of [Ru (bpy) 2 (NHC-SR)] 2+ and
[Ru (bpy) 2 (NHC-S (O) R)] 2+ were prepared and investigated by X-ray crystallography …
[Ru (bpy) 2 (NHC-S (O) R)] 2+ were prepared and investigated by X-ray crystallography …
Interrelations between Linkage Isomers of an Efficient Square‐planar Nickel (II) Nitrite Photoswitch in the Solid State
K Potempa, KA Deresz, J Jankowska… - … A European Journal, 2023 - Wiley Online Library
An efficient nitrite nickel (II) photoswitch, with the 1‐phenyl‐2‐hydroxyimino‐3‐[(2'‐
dimethylamino) ethyl] imino‐1‐propanone moiety used as the ancillary ligand, is reported. In …
dimethylamino) ethyl] imino‐1‐propanone moiety used as the ancillary ligand, is reported. In …
[HTML][HTML] Low-energy optical switching of SO 2 linkage isomerisation in single crystals of a ruthenium-based coordination complex
JM Cole, DJ Gosztola, SO Sylvester - RSC advances, 2021 - pubs.rsc.org
Single crystals that behave as optical switches are desirable for a wide range of
applications, from optical sensors to read–write memory media. A series of ruthenium-based …
applications, from optical sensors to read–write memory media. A series of ruthenium-based …
Systems Approach of Photoisomerization Metrology for Single-Crystal Optical Actuators: A Case Study of [Ru(SO2)(NH3)4Cl]Cl
JM Cole, DJ Gosztola… - The Journal of …, 2020 - ACS Publications
Chemicals that undergo photoisomerization in their single-crystal form may act as optical
actuators or sensors. It is important to determine the molecular-scale characteristics of this …
actuators or sensors. It is important to determine the molecular-scale characteristics of this …