Selective oxidation of the γ-C–H bonds from abundant amine feedstocks via palladium
catalysis is a valuable transformation in synthesis and medicinal chemistry. Despite …

In the present study, the mechanism of a cobalt-catalyzed hydroacylation reaction between
aldehydes and 1, 6-enynes and the origin of its stereoselectivity have been systematically …

The palladium‐catalyzed reaction of aromatic amides with maleimides results in the
formation of a double C− H bond activation product, which occurs at both the benzylic and …

Carboxylic acids are ubiquitous functional groups present in many bio‐relevant molecules,
including drugs and amino acids. In general, α‐and β− C (sp3)− H bonds of carboxylic acids …

We report intra-and intermolecular γ-amino C (sp3)–H functionalization of aliphatic amines
using a vinylsulfone-based HAT (hydrogen atom transfer) auxiliary and a triple catalysis …

Chemical transformations involving the pyrenylglycine motif (an unnatural amino acid) and
practical methods toward it are seldom known. This work aimed at developing a method for …

In this paper, we report the Pd (II)-catalyzed, picolinamide DG-aided sp 2 γ-C–H
functionalization and expansion of the library of enantiopure α-methylbenzylamine and …

This paper reports the synthesis of enantiopure aryl alkyl ethers via the Pd (II)‐catalyzed
picolinamide‐aided γ‐C (sp2)− H alkoxylation of various enantiopure α‐alkylbenzylamine …

Expanding the availability, scope, and limitations of directing groups (DGs) for executing the
site‐selective C− H activation and functionalization and substrate scope development are …

This paper describes the Pd (II)‐catalyzed, picolinamide‐directing‐group‐aided C (sp2)− H
(ortho) functionalization of racemic and enantiopure β‐phenylalanines and 3‐amino‐3 …