Hydrogenation of carboxylic acids, esters, and related compounds over heterogeneous catalysts: a step toward sustainable and carbon-neutral processes

R Qu, K Junge, M Beller - Chemical Reviews, 2023 - ACS Publications
The catalytic hydrogenation of esters and carboxylic acids represents a fundamental and
important class of organic transformations, which is widely applied in energy, environmental …

Plasma-assisted CO2 reforming of methane over Ni-based catalysts: Promoting role of Ag and Sn secondary metals

T Suttikul, S Nuchdang, D Rattanaphra… - International Journal of …, 2022 - Elsevier
Carbon dioxide (CO 2) and methane (CH 4) are the primary greenhouse gases (GHGs) that
drive global climate change. CO 2 reforming of CH 4 or dry reforming of CH 4 (DRM) is used …

Efficient catalytic amination of diols to diamines over Cu/ZnO/γ-Al2O3

X Cai, Y Ke, B Wang, Y Zeng, L Chen, Y Li, G Bai… - Molecular …, 2021 - Elsevier
Catalytic amination of diols with dimethylamine is a promising approach for the preparation
of tetramethyl diamines. In this work, a series of Cu/ZnO/γ-Al 2 O 3 catalysts were developed …

[HTML][HTML] 助剂对于Cu/ZnO 催化剂结构特征及催化草酸二甲酯加氢合成乙二醇反应性能的影响

孔祥鹏, 游新明, 元培红, 吴跃焕, 王瑞虹… - 燃料化学学报(中 …, 2023 - rlhxxb.sxicc.ac.cn
采用共沉淀法合成了掺杂不同助剂的Cu-M/ZnO (Cu: ZnO 物质的量比= 5∶ 4, M= Zr 4+, Al 3+,
Mg 2+, 助剂含量为4.0%) 用于催化草酸二甲酯(Dimethyl oxalate, DMO) 选择加氢反应催化剂 …

Understanding of the key properties of supported Cu-based catalysts and their influence on ester hydrogenolysis

J Aubrecht, V Pospelova, O Kikhtyanin, M Lhotka… - Catalysis Today, 2022 - Elsevier
The application of Cr-free Cu-based catalysts in ester hydrogenolysis is a modern
environmentally-friendly research approach. The comprehensive study of four supported Cu …

Mesoporous Cu catalysts for dimethyl oxalate selective hydrogenation: impact of the Cu/Al interface on the textural properties and catalytic behavior

X Kong, X You, P Yuan, M Wang, Y Wu… - …, 2022 - Wiley Online Library
In this paper, mesoporous monometallic Cu catalysts reinforced by the Al3+ dopants with
different chemical features were successfully synthesized by controlling the preparation …

Effect of Calcination Temperature on the Textural Properties and Catalytic Behavior of the Al2O3 Doped Mesoporous Monometallic Cu Catalysts in Dimethyl Oxalate …

X Kong, Y Wu, P Yuan, M Wang, P Wu, L Ding, R Wang… - Catalysis Letters, 2021 - Springer
Al 2 O 3 doped mesoporous monometallic Cu catalysts were successfully synthesized
though the self-assembly Cu species derived from the oxalate precursor undergoing thermal …

[HTML][HTML] 煤经草酸酯制高价值含氧化学品的技术进展

张红旭, 刘蝈蝈, 俞佳枫, 孙剑 - 燃料化学学报(中英文), 2023 - rlhxxb.sxicc.ac.cn
中国的能源结构是富煤少油, 开发煤炭资源的高效清洁利用是中国重点发展方向.
煤经合成气羰基化后可以合成草酸酯(DMO), 进一步加氢可获得具有高附加值的含氧化学品 …

Role of the Cu dopant in the textural and catalytic features of the Co/ZnO catalyst for dimethyl oxalate selective hydrogenation

X Kong, R Wu, P Yuan, Y Wu, R Wang… - Journal of Chemical …, 2023 - Wiley Online Library
BACKGROUND Converting the syngas‐derived dimethyl oxalate (DMO) intermediate to
versatile simple diols (ethylene glycol, EG) has been deemed as a promising chemical …

Influence of dopants on the structure and catalytic features of the Cu/ZnO catalyst for dimethyl oxalate hydrogenation to ethylene glycol

X KONG, X YOU, P YUAN, Y WU, R WANG… - Journal of Fuel Chemistry …, 2023 - Elsevier
Abstract The Cu-M/ZnO catalysts (M= Zr 4+, Al 3+ and Mg 2+) for dimethyl oxalate (DMO)
selective hydrogenation to ethylene glycol (EG) were synthesized by the co-precipitation …