Circularly polarized luminescence of helicenes: A data‐informed insight

M Cei, L Di Bari, F Zinna - Chirality, 2023 - Wiley Online Library
Helicenes are an interesting scaffold for chiroptical properties and in particular circularly
polarized luminescence (CPL). In this short review, we collect the luminescence (glum) and …

Synthesis of π-conjugated chiral organoborane macrocycles with blue to near-infrared emissions and the diradical character of cations

F Zhao, J Zhao, H Liu, Y Wang, J Duan… - Journal of the …, 2023 - ACS Publications
Highly emissive π-conjugated macrocycles with tunable circularly polarized luminescence
(CPL) have sparked theoretical and synthetic interests in recent years. Herein, we report a …

Chiral Triarylborane‐Based Small Organic Molecules for Circularly Polarized Luminescence

M Wang, CH Zhao - The Chemical Record, 2022 - Wiley Online Library
Circularly polarized luminescence (CPL) has shown promising application potentials in 3D
display, optical data storage, smart sensors/probers, CPL lasers, and light source for …

Polycationic Open‐Shell Cyclophanes: Synthesis of Electron‐Rich Chiral Macrocycles, and Redox‐Dependent Electronic States

Y Shi, C Li, J Di, Y Xue, Y Jia, J Duan, X Hu… - Angewandte …, 2024 - Wiley Online Library
π‐Conjugated chiral nanorings with intriguing electronic structures and chiroptical
properties have attracted considerable interests in synthetic chemistry and materials …

Turn-on circularly polarized luminescence for dynamical-racemic and large-hollow AIE macrocycle based on selective recognition for ursolic acid

S Chen, M Zhu, X Xu, H Guo, F Yang - Dyes and Pigments, 2023 - Elsevier
The macrocycles with the features of large cavity, optical property and CPL response to
guest simultaneously are rarely reported but very attractive based on their potential …

Fluorescence Filter Nanoarchitectonics with Polydiacetylene‐Based Supramolecular Chiral Gel for Generating Tunable Circularly Polarized Luminescence

D Zhai, J Jiang, C Yuan, D Wang… - Advanced Optical …, 2023 - Wiley Online Library
Circularly polarized luminescence (CPL) can be generated from chiral luminescent
materials. It can also be achieved from achiral emissive dyes by selectively filtering their …

[5] Helicene-based chiral triarylboranes with large luminescence dissymmetry factors over a 10− 2 level: synthesis and design strategy via isomeric tuning of steric …

F Zhao, J Zhao, Y Wang, HT Liu, Q Shang… - Dalton …, 2022 - pubs.rsc.org
Constructing chiral luminescent systems with both large luminescence dissymmetry factor
(glum) and high luminous efficiency has been considered a great challenge. We herein …

Highly sensitive fluorescence response of [2.2] paracyclophane modified D− A type chromophores to trace water, pH, acidic gases and formaldehyde

H Ji, W Duan, Y Huo, W Liu, X Huang, Y Wang… - Dyes and …, 2022 - Elsevier
Abstract Donor (D)− acceptor (A) type compounds have drawn significant attraction recently
due to their large Stokes shifted emission and easy-tunable emissive behaviour. Herein, a …

Synthesis and Stereodynamic and Emission Properties of Dissymmetric Bis-Aryl Carbazole Boranes and Identification of a CPL-Active B–C Atropisomeric Compound

D Pecorari, E Giuliani, A Mazzanti… - The Journal of …, 2023 - ACS Publications
We synthesized bis-aryl carbazole borane derivatives having emissive properties and axial
chirality. The resolution of a thermally stable atropisomeric pair (compound 1b), due to a B …

Synthesis of Nonsymmetric NBN-Embedded [6]-and [7] Helicenes with Amplified Activities

Y Jiao, Z Sun, Z Wang, Y Fu, F Zhang - Organic Letters, 2023 - ACS Publications
Two C 1-symmetric heterohelicenes were constructed by nonsymmetrically extending the
ortho-fused structures of a C 2 v-symmetric NBN-embedded phenalene derivative and …