Exovinylene Cyclic Carbonates: Multifaceted CO2‐Based Building Blocks for Modern Chemistry and Polymer Science

C Ngassam Tounzoua, B Grignard… - Angewandte …, 2022 - Wiley Online Library
Carbon dioxide is a renewable, inexhaustible, and cheap alternative to fossil resources for
the production of fine chemicals and plastics. It can notably be converted into exovinylene …

Organocatalytic carbon–sulfur bond-forming reactions

P Chauhan, S Mahajan, D Enders - Chemical reviews, 2014 - ACS Publications
Carbon− heteroatom bond formations are very important reactions in organic synthesis and
have attracted the interest of many synthetic organic chemists, leading them to develop new …

Data-mining for sulfur and fluorine: An evaluation of pharmaceuticals to reveal opportunities for drug design and discovery: Miniperspective

EA Ilardi, E Vitaku, JT Njardarson - Journal of medicinal chemistry, 2014 - ACS Publications
Among carbon, hydrogen, oxygen, and nitrogen, sulfur and fluorine are both leading
constituents of the pharmaceuticals that comprise our medicinal history. In efforts to stimulate …

A visible‐light‐harvesting covalent organic framework bearing single nickel sites as a highly efficient sulfur–carbon cross‐coupling dual catalyst

H Chen, W Liu, A Laemont, C Krishnaraj… - Angewandte …, 2021 - Wiley Online Library
Abstract Covalent Organic Frameworks (COFs) have recently emerged as light‐harvesting
devices, as well as elegant heterogeneous catalysts. The combination of these two …

The energy-transfer-enabled biocompatible disulfide–ene reaction

M Teders, C Henkel, L Anhäuser, F Strieth-Kalthoff… - Nature Chemistry, 2018 - nature.com
Sulfur-containing molecules participate in many essential biological processes. Of utmost
importance is the methylthioether moiety, present in the proteinogenic amino acid …

Catalytic, enantioselective sulfenofunctionalization of alkenes: development and recent advances

A Matviitsuk, JL Panger… - Angewandte Chemie …, 2020 - Wiley Online Library
The last decade has witnessed a burgeoning of new methods for the enantioselective vicinal
difunctionalization of alkenes initiated by electrophilic sulfenyl group transfer. The addition of …

Regio‐and Enantioselective Synthesis of Sulfone‐Bearing Quaternary Carbon Stereocenters by Pd‐Catalyzed Allylic Substitution

A Khan, H Zhao, M Zhang, S Khan… - Angewandte Chemie …, 2020 - Wiley Online Library
Chiral sulfones are of great importance in medicinal chemistry and chemical synthesis.
Efficient methods for preparing enantiomerically enriched sulfone‐containing molecules can …

Catalytic enantioselective construction of sulfur-containing tetrasubstituted carbon stereocenters

JS Yu, HM Huang, PG Ding, XS Hu, F Zhou… - ACS Catalysis, 2016 - ACS Publications
Sulfur-containing tetrasubstituted carbon stereocenters are widely present in natural
products, drugs, and biologically active compounds. Catalytic enantioselective construction …

High-performance liquid chromatographic assay of the methyl and nucleotide metabolites of 6-mercaptopurine: quantitation of red blood cell 6-thioguanine nucleotide …

L Lennard, HJ Singleton - … of Chromatography B: Biomedical Sciences and …, 1992 - Elsevier
A reversed-phase high-performance liquid chromatographic assay was developed to
quantify intracellular metabolites of the cytotoxic drug 6-mercaptopurine in the human red …

Cation Control of Diastereoselectivity in Iridium-Catalyzed Allylic Substitutions. Formation of Enantioenriched Tertiary Alcohols and Thioethers by Allylation of 5H-Oxazol-4-ones …

W Chen, JF Hartwig - Journal of the American Chemical Society, 2014 - ACS Publications
We report highly diastereo-and enantioselective allylations of substituted 5H-oxazol-4-ones
and 5H-thiazol-4-ones catalyzed by a metallacyclic iridium complex. Enantioselective Ir …