Decarboxylative halogenation, or halodecarboxylation, represents one of the fundamental
key methods for the synthesis of ubiquitous organic halides. The method is based on …

Currently, the chemistry of organofluorine compounds is a leading and rapidly developing
area of organic chemistry. Fluorine present in a molecule largely determines its specific …

We report the first highly enantioselective construction of silicon‐stereocenters by
asymmetric enamine catalysis. An unprecedented desymmetric intramolecular aldolization …

The emergence of drug resistance and low specificity with side effects are the significant
challenges in pharmaceutical sectors for control of cancer nowadays. Notwithstanding, this …

A highly enantio-and regio-selective Markovnikov hydromonofluoro (methyl) alkylation of 1,
3-dienes was developed using redox-neutral nickel catalysis. It provided a facile strategy to …

The majority of pharmaceuticals and other organic compounds incorporating radiotracers
that are considered foreign to the body undergo metabolic changes in vivo. Metabolic …

N‐Trifluoromethylated organics may be applied in drug design, agrochemical synthesis, and
materials science, among other areas. Yet, despite recent advances in the synthesis of …

A cobalt-catalyzed aminofluorination reaction of styrenes with N-fluorosulfonamides serving
as both the amination and fluorination agents has been developed. The switch of selectivity …

Tertiary cyclopropanols react rapidly with Togni reagent in methanol at room temperature in
the presence of catalytic amounts (3 mol%) of CuCl affording β-trifluoromethyl ketones in 65 …

Highly selective direct monofluorination of indoles and arenes was developed through an
approach that allows site‐specific solubility of substrate and fluorine source in the micelle …