Chemical Flexibility of Atomically Precise Metal Clusters

S Li, NN Li, XY Dong, SQ Zang, TCW Mak - Chemical Reviews, 2024 - ACS Publications
Ligand-protected metal clusters possess hybrid properties that seamlessly combine an
inorganic core with an organic ligand shell, imparting them exceptional chemical flexibility …

Harnessing triplet excitons: Advances in luminescence metal coordination compounds

L Geng, R Sun, DS Zhang, MH Yu, Z Chang… - Coordination Chemistry …, 2024 - Elsevier
The efficient utilization of triplet excitons serves as a key driver for the advancement of
luminescence materials. Therefore, coordination compounds based on phosphorescence …

Site-Recognition-Induced Structural and Photoluminescent Evolution of the Gold–Pincer Nanocluster

Y Zhang, W Zhang, TS Zhang, C Ge… - Journal of the …, 2024 - ACS Publications
The induced structural transformation provides an efficient way to precisely modulate the
fine structures and the corresponding performance of gold nanoclusters, thus constituting …

Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters

Z Zhao, M Zhao, L Deng, Q Li, J Zhang, H Su… - Chemical …, 2024 - pubs.rsc.org
Two structurally new Lindqvist hexaniobate-templated silver thiolate clusters,[Nb6O19@
Ag45 (iPrS) 23 (CH3COO) 14](Ag45) and (H3O) 4 [Nb6O19@ Ag41KS2. 5O2 (H2O) 7.5 …

BINOL‐Based Chiral Macrocycles and Cages

Y Yu, Y Hu, C Ning, W Shi, A Yang… - Angewandte Chemie …, 2024 - Wiley Online Library
Chirality, a fundamental principle in chemistry, biology, and medicine, is prevalent in nature
and in organisms. Chiral molecules, such as DNA, RNA, and proteins, are crucial in …

DNA Framework-Guided Self-Limiting Aggregation for Highly Luminescent Metal Cluster Nanoaggregates

H Zheng, Y Zhou, B Yan, G Zhou, X Cheng… - Journal of the …, 2024 - ACS Publications
The photoluminescent properties of atomically precise metal nanoclusters (MCs) have
garnered significant attention in the fields of chemical sensing and biological imaging …

Incorporation of the 99TcO4 Anion within the Ag24(C≡CtBu)204+ Cluster Unveiling the Unique Shell-to-Core Charge Transfer

Y Tao, N Luan, C Yang, J Sun, K Li, X Dai… - Journal of the …, 2024 - ACS Publications
We present the first example of an 99TcO4–anion entrapped within the cavity of a silver
cluster, revealing an unprecedented photoinduced charge transfer phenomenon.[Ag24 (C≡ …

Application of gold nanoclusters in fluorescence sensing and biological detection

K Tan, H Ma, X Mu, Z Wang, Q Wang, H Wang… - Analytical and …, 2024 - Springer
Abstract Gold nanoclusters (Au NCs) exhibit broad fluorescent spectra from visible to near-
infrared regions and good enzyme-mimicking catalytic activities. Combined with excellent …

[HTML][HTML] Electrocatalytic and photocatalytic activities of two alkynyl Ag20 cage clusters involved ligand exchange between PhCOO− and CF3COO−

YF Tan, L Li, K Zhou, GM Liang, J Sun, JY Ji… - Journal of Saudi Chemical …, 2024 - Elsevier
Two silver alkynyl clusters,[(CO 3 2−)@ Ag 20 (t BuC≡ C) 14 (PhCOO) 3 (CF 3 COO)](1)
and [(CO 3 2−)@ Ag 20 (t BuC≡ C) 14 (PhCOO)(CF 3 COO) 3](2), composed of alkynyl Ag …

Atomically Precise Metal Nanoclusters for Photocatalytic Water Splitting

Y Liu, Y Wang, N Pinna - ACS Materials Letters, 2024 - ACS Publications
Atomically precise nanoclusters (NCs), which bridge the gap between molecular chemistry
and nanochemistry, are drawing significant attention in various fields. Due to their discrete …