Silacyclobutanes (SCBs), as a key member of the organosilicon family, have received
considerable attention in synthetic chemistry since the silicon–carbon bond can be …

Transition-metal-catalyzed intermolecular annulation of silicon reagents with organic
molecules is still underdeveloped due to the scarcity of silicon reagent types and their …

The exploitation of chirality at silicon in asymmetric catalysis is one of the most intriguing and
challenging tasks in synthetic chemistry. In particular, construction of enantioenriched …

The development of a straightforward strategy to obtain enantioenriched silicon‐stereogenic
benzosiloles remains a challenging yet appealing synthesis venture due to their potential …

Silaspiranes have attracted particular attention due to their chiral spiro‐silicon center, which
serves as an ideal carbon isostere and can endow spiro‐analogs with distinct properties …

We report an efficient strategy that combines organic photoredox and hydrogen atom
transfer to deliver gem-difluoroallylsilanes via defluorinative silylation of α …

The study of new C–H silylation reagents and reactions remains an important topic. We
reported that under Rh catalysis, silacyclobutanes (SCBs) for the first time were able to react …

Due to the widespread application of various organosilicon compounds in material science,
electronic devices and pharmaceutical research, it is of great significance to develop green …

Silacycle is one of the most essential core frameworks in silicon-containing functional
molecules. However, the structural diversity of silacycles has been largely limited due to the …

Silicon/carbon switching strategy, known as silasubstitution, plays an important role in drug
discovery and material science. However, there is a dearth of efficient and precisely …