This review is focused on the analysis of current data on new methods of alkenylation of
arenes and heteroarenes with alkynes by transition metal catalyzed reactions …

Transition-metal (TM)-catalyzed hydroarylation reactions of alkynes have received much
attention, because they enable the net insertion of alkyne C–C triple bonds into C–H bonds …

A visible-light initiated oxidative cyclization of phenyl propiolates with sulfinic acids has been
developed. The arylsulfonylation of alkynes was performed at room temperature under metal …

Though often perceived as the simple metaphorical hybrid of synthetic inorganic and
organic chemistry, synthetic organometallic chemistry continues to vigorously differentiate …

Benzofuran derivatives are ubiquitous in natural products,[1] agrochemicals,[2]
pharmaceuticals,[3, 4] and organic materials.[5] Particularly, 2-arylbenzofurans are widely …

Coumarins reign their class term, which is the vulgarity name of the plant belongs to the
Fabaceae family named tonka bean. The parent compound, coumarin itself, was novally …

The asymmetric allylic substitution of allyl phosphates with aryl‐and alkenylboronates
catalyzed by a copper/N‐heterocyclic carbene complex was developed and the γ …

A straightforward and atom-economical base-free palladium-catalyzed regioselective direct
arylation of coumarins and chromenones is devised. This protocol is compatible with a wide …

An efficient protocol for the direct synthesis of 4-arylcoumarins via palladium-catalyzed
oxidative Heck coupling reaction of coumarins and arylboronic acids was developed. 4 …

Three-component coupling using arynes and DMF: straightforward access to coumarins via
ortho-quinone methides - Chemical Communications (RSC Publishing) DOI:10.1039/C1CC11955A …