[HTML][HTML] Photo-induced spirocyclization of biaryl ynones with ammonium thiocyanate: access to thiocyanate-featured spiro [5, 5] trienones

S Chen, Q Yan, J Fan, C Guo, L Li, ZQ Liu, Z Li - Green Chemistry, 2023 - pubs.rsc.org
Photo-promoted mild tandem 6-exo-trig spirocyclization of biaryl ynones with ammonium
thiocyanate has been developed to access thiocyanate-containing spiro [5, 5] trienones with …

Nitro-Spirocyclization of Biaryl Ynones with tert-Butyl Nitrite: Access to NO2-Substituted Spiro[5,5]trienones

Y Li, L Li, C Guo, Q Yan, H Zhou, Y Wang… - The Journal of …, 2023 - ACS Publications
A metal/peroxide-free involved simple cascade 6-exo-trig spirocyclization of tert-butyl nitrite
with biaryl ynones has been finished, which resulted in various NO2-modified spiro [5, 5] …

[HTML][HTML] Synthesis of polychloromethylated and halogenated spiro [5, 5] trienones via dearomative spirocyclization of biaryl ynones

JN Li, ZJ Li, LY Shen, P Li, Y Zhang… - Organic & Biomolecular …, 2022 - pubs.rsc.org
We disclosed a selective polychloromethylation and halogenation reaction of alkynes via a
radical addition/spirocyclization cascade sequence, in which polyhaloalkanes were used as …

[HTML][HTML] Visible light-induced selenylative spirocyclization of biaryl ynones toward the formation of selenated spiro [5.5] trienones

Z Chen, X Zheng, SF Zhou, X Cui - Organic & Biomolecular Chemistry, 2022 - pubs.rsc.org
A visible-light induced dearomative cascade cyclization of biaryl ynones with diselenides
under photocatalyst and external additive-free conditions has been explored, giving a series …

[HTML][HTML] Recent Developments in the Synthesis of Organoselenium Compounds Based on the Reactions of Organic Diselenides with Acetylenes

MV Musalov, VA Potapov, MV Musalova, SV Amosova… - Catalysts, 2023 - mdpi.com
The last decade has witnessed significant progress in the development of novel synthetic
methods for the preparation of a variety of new functionalized and condensed compounds …

Access to Diverse Seleno-spirocyclohexadienones via Ag(II)-Catalyzed Selenylative ipso-Annulation with Se and Boronic Acids

C Raji Reddy, M Subbarao, DH Kolgave… - ACS …, 2022 - ACS Publications
An efficient and straightforward synthesis of diversified seleno-azaspiro-2, 5-
cyclohexadienones from N-(4-methoxy aryl) propiolamides using elemental selenium and …

Synthesis of chalcogenylchromenes through cyclization of propargylic Aryl ethers

PS Hellwig, AM Barcellos, R Cargnelutti… - The Journal of …, 2022 - ACS Publications
We describe here for the first time the synthesis of 2-(chalcogenyl)-3 H-benzo [f] chromenes
and the new 3-(phenylselanyl)-2 H-chromenes by the radical or electrophilic cyclization of …

[HTML][HTML] Radical selenylative cyclization of trifluoromethyl propargyl imines for the synthesis of trifluoromethyl-and seleno-azaspiro [4, 5]-tetraenones and quinolines

G Wei, J Zhang, H Wang, Z Chen, XF Wu - Organic & Biomolecular …, 2023 - pubs.rsc.org
A radical selenylative cyclization of trifluoromethyl propargyl imines with diselenides for the
regiodivergent construction of diversely functionalized azaspiro [4, 5]-tetraenones and …

Visible Light Promoted Brominative Dearomatization of Biaryl Ynones to Spirocycles

B Roy, P Kuila, D Sarkar - The Journal of Organic Chemistry, 2023 - ACS Publications
Bromine induced spiro cyclization of biaryl ynones facilitated the synthesis of spiro [5, 5]
trienones suitable for extended functionality at the C (3′) position. Herein, a step-economic …

[HTML][HTML] Synthesis and biological evaluation of 5-chalcogenyl-benzo [h] quinolines via photocyclization of arylethynylpyridine derivatives

TJ Peglow, CC Martins, KP da Motta… - New Journal of …, 2022 - pubs.rsc.org
A new and efficient method for the synthesis of 6-organyl-5-(arylselanyl) benzo [h]
quinolines via visible light-promoted intramolecular ortho-cyclization of 2-aryl-3 …