Methane transformation by photocatalysis

X Li, C Wang, J Tang - Nature Reviews Materials, 2022 - nature.com
Methane hydrate and shale gas are predicted to have substantial reserves, far beyond the
sum of other fossil fuels. Using methane instead of crude oil as a building block is, thus, a …

[PDF][PDF] Principles and applications of photothermal catalysis

C Song, Z Wang, Z Yin, D Xiao, D Ma - Chem Catalysis, 2022 - cell.com
Solar energy provides an alternative, sustainable, and clean source of energy to meet the
global energy demands without extra carbon emissions. However, the utilization efficiency of …

A selective Au-ZnO/TiO2 hybrid photocatalyst for oxidative coupling of methane to ethane with dioxygen

S Song, H Song, L Li, S Wang, W Chu, K Peng… - Nature Catalysis, 2021 - nature.com
Direct oxidation of methane to valuable chemicals is a great challenge as catalysts with both
high activity and selectivity for the activation of inert C–H bonds are required. Here, we …

[HTML][HTML] Synergy of Pd atoms and oxygen vacancies on In2O3 for methane conversion under visible light

L Luo, L Fu, H Liu, Y Xu, J Xing, CR Chang… - Nature …, 2022 - nature.com
Methane (CH4) oxidation to high value chemicals under mild conditions through
photocatalysis is a sustainable and appealing pathway, nevertheless confronting the critical …

[PDF][PDF] Toward solar-driven carbon recycling

H Lin, S Luo, H Zhang, J Ye - Joule, 2022 - cell.com
Carbon recycling will become a dominant trend toward alleviating extreme climate change
and coping with the increasing energy demand in the coming years. Solar-driven strategies …

Binary Au–Cu reaction sites decorated ZnO for selective methane oxidation to C1 oxygenates with nearly 100% selectivity at room temperature

L Luo, Z Gong, Y Xu, J Ma, H Liu, J Xing… - Journal of the American …, 2021 - ACS Publications
Direct and efficient oxidation of methane to methanol and the related liquid oxygenates
provides a promising pathway for sustainable chemical industry, while still remaining an …

[HTML][HTML] Efficient and selective photocatalytic CH4 conversion to CH3OH with O2 by controlling overoxidation on TiO2

N Feng, H Lin, H Song, L Yang, D Tang… - Nature …, 2021 - nature.com
The conversion of photocatalytic methane into methanol in high yield with selectivity remains
a huge challenge due to unavoidable overoxidation. Here, the photocatalytic oxidation of …

Engineering lattice disorder on a photocatalyst: photochromic BiOBr nanosheets enhance activation of aromatic C–H bonds via water oxidation

X Cao, A Huang, C Liang, HC Chen… - Journal of the …, 2022 - ACS Publications
Solar-driven photocatalytic reactions can mildly activate hydrocarbon C–H bonds to produce
value-added chemicals. However, the inefficient utilization of photogenerated carriers …

Photocatalytic conversion of methane: recent advancements and prospects

Q Li, Y Ouyang, H Li, L Wang, J Zeng - Angewandte Chemie, 2022 - Wiley Online Library
Abundant and affordable methane is not only a high‐quality fossil fuel, it is also a raw
material for the synthesis of value‐added chemicals. Solar‐energy‐driven conversion of …

Selective photocatalytic oxidative coupling of methane via regulating methyl intermediates over metal/ZnO nanoparticles

P Wang, R Shi, Y Zhao, Z Li, J Zhao, J Zhao… - Angewandte …, 2023 - Wiley Online Library
Methane conversion to higher hydrocarbons requires harsh reaction conditions due to high
energy barriers associated with C− H bond activation. Herein, we report a systematic …