Understanding ligand-protected noble metal nanoclusters at work

MF Matus, H Häkkinen - Nature Reviews Materials, 2023 - nature.com
Ligand-protected noble metal nanoclusters, commonly termed 'monolayer-protected metal
clusters'(MPCs), comprise a common set of structures with an inorganic core stabilized by an …

Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R Jin - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Eight-Electron Superatomic Cu31 Nanocluster with Chiral Kernel and NIR-II Emission

T Jia, ZJ Guan, C Zhang, XZ Zhu, YX Chen… - Journal of the …, 2023 - ACS Publications
Owing to the inherent instability caused by the low Cu (I)/Cu (0) half-cell reduction potential,
Cu (0)-containing copper nanoclusters are quite uncommon in comparison to their Ag and …

Ultrasmall coinage metal nanoclusters as promising theranostic probes for biomedical applications

G Yang, Z Wang, F Du, F Jiang, X Yuan… - Journal of the American …, 2023 - ACS Publications
Ultrasmall coinage metal nanoclusters (NCs,< 3 nm) have emerged as a novel class of
theranostic probes due to their atomically precise size and engineered physicochemical …

Suppression of kernel vibrations by layer-by-layer ligand engineering boosts photoluminescence efficiency of gold nanoclusters

Y Zhong, J Zhang, T Li, W Xu, Q Yao, M Lu… - Nature …, 2023 - nature.com
The restriction of structural vibration has assumed great importance in attaining bright
emission of luminescent metal nanoclusters (NCs), where tremendous efforts are devoted to …

Ligand-protected metal nanoclusters as low-loss, highly polarized emitters for optical waveguides

X Wang, B Yin, L Jiang, C Yang, Y Liu, G Zou, S Chen… - Science, 2023 - science.org
Photoluminescent molecules and nanomaterials have potential applications as active
waveguides, but such a use has often been limited by high optical losses and complex …

Shell engineering to achieve modification and assembly of atomically-precise silver clusters

Y Jin, C Zhang, XY Dong, SQ Zang… - Chemical Society …, 2021 - pubs.rsc.org
Continuing research on the preparation and structural determination of monolayer-protected
silver clusters has been performed. The compounds include mixed-valence Ag0/1+ clusters …

Fabrication strategies for metal-organic framework electrochemical biosensors and their applications

X Fu, B Ding, D D'Alessandro - Coordination Chemistry Reviews, 2023 - Elsevier
Metal-organic frameworks (MOFs) are a class of functional porous three-dimensional
framework materials exhibiting unique chemical properties. Owing to the multifunctional …

On-off-on fluorescent nanosensing: Materials, detection strategies and recent food applications

H He, DW Sun, Z Wu, H Pu, Q Wei - Trends in Food Science & Technology, 2022 - Elsevier
Background The detection of food quality and safety is important in the whole food supply
chain. In recent years, fluorescent detection technology has been extensively applied in food …

Endohedrally doped cage clusters

J Zhao, Q Du, S Zhou, V Kumar - Chemical Reviews, 2020 - ACS Publications
The discovery of carbon fullerene cages and their solids opened a new avenue to build
materials from stable cage clusters as “artificial atoms” or “superatoms” instead of atoms …