The chemistry and applications of multimetallic salen complexes

RM Clarke, T Storr - Dalton Transactions, 2014 - pubs.rsc.org
Multimetallic salen complexes have found utility in a number of fields from materials
chemistry to catalysis. The objective of this perspective is to discuss the development of new …

Synthesis, characterization and biological evaluation of piperazine embedded copper complexes

R Kant, S Maji - Inorganica Chimica Acta, 2023 - Elsevier
In this paper, we report the synthesis, and characterization of three piperazine based
multidentate ligands and their copper complexes. Ligands and complexes were …

Nickel(II) Complex of a Hexadentate Ligand with Two o-Iminosemiquinonato(1−) π-Radical Units and Its Monocation and Dication

A Ali, D Dhar, SK Barman, F Lloret… - Inorganic …, 2016 - ACS Publications
Aerobic reaction of a hexadentate redox-active o-aminophenol-based ligand, H4L3= N, N′-
bis (2-hydroxy-3, 5-di-tert-butylphenyl)-2, 2′-diamino (diphenyldithio)-ethane, in CH3OH …

Electronic Structure Description of a Doubly Oxidized Bimetallic Cobalt Complex with Proradical Ligands

RM Clarke, K Hazin, JR Thompson, D Savard… - Inorganic …, 2016 - ACS Publications
The geometric and electronic structure of a doubly oxidized bimetallic Co complex
containing two redox-active salen moieties connected via a 1, 2-phenylene linker was …

Scrutinizing the noninnocence of quinone ligands in ruthenium complexes: insights from structural, electronic, energy, and effective oxidation state analyses

G Skara, M Gimferrer, F De Proft, P Salvador… - Inorganic …, 2016 - ACS Publications
The most relevant manifestations of ligand noninnocence of quinone and bipyridine
derivatives are thoroughly scrutinized and discussed through an extensive and systematic …

Palladium(II) Complex of a Redox-Active Amidophenolate-Based O,N,S,N Ligand: Its Monocation and Dication and Reactivity with PPh3

A Ali, SK Barman, R Mukherjee - Inorganic Chemistry, 2015 - ACS Publications
A new potentially tetradentate redox-active o-aminophenol-based ligand, H2L= 2-(2-
ethylthio) pyridine-anilino-4, 6-di-tert-butylphenol, reacts with PdII (O2CCH3) 2 in CH3OH in …

Class III delocalization and exciton coupling in a bimetallic bis‐ligand radical complex

TJ Dunn, L Chiang, CF Ramogida… - … A European Journal, 2013 - Wiley Online Library
The geometric and electronic structure of an oxidized bimetallic Ni complex incorporating
two redox‐active Schiff‐base ligands connected via a 1, 2‐phenylene linker has been …

Shape‐Persistent (Pt‐salphen)2 Phosphorescent Coordination Frameworks: Structural Insights and Selective Perturbations

Z Guo, SM Yiu, MCW Chan - Chemistry–A European Journal, 2013 - Wiley Online Library
The development of molecular frameworks derived from binuclear platinum (II) aromatic
Schiff base (salphen) complexes and their supramolecular chemistry have been undertaken …

A non-innocent salen naphthalene ligand and its Co2+, Ni2+ and Cu2+ metal complexes: Structural, electrochemical, and spectroscopic characterization and …

K Gutierrez, J Corchado, S Lin, Z Chen… - Inorganica Chimica Acta, 2018 - Elsevier
Three mononuclear metal complexes of Co 2+, Ni 2+ and Cu 2+ with the Salen type ligand
((2, 2′-[(1-methyl-1, 2-ethanediyl) bis (nitriloethylidyne)] bis (1-naphthalenol)), H 2 …

[HTML][HTML] Exploiting exciton coupling of ligand radical intervalence charge transfer transitions to tune NIR absorption

RM Clarke, T Jeen, S Rigo, JR Thompson… - Chemical …, 2018 - pubs.rsc.org
We detail the rational design of a series of bimetallic bis-ligand radical Ni salen complexes
in which the relative orientation of the ligand radical chromophores provides a mechanism to …