Catalytic reactions of acetylene: a feedstock for the chemical industry revisited

IT Trotus, T Zimmermann, F Schuth - Chemical reviews, 2014 - ACS Publications
With the start of the industrial production of acetaldehyde by acetylene hydration in 1916,
acetylene became one of the most important raw materials for coal-based chemistry in the …

[HTML][HTML] Acetylene in organic synthesis: Recent progress and new uses

VV Voronin, MS Ledovskaya, AS Bogachenkov… - Molecules, 2018 - mdpi.com
Recent progress in the leading synthetic applications of acetylene is discussed from the
prospect of rapid development and novel opportunities. A diversity of reactions involving the …

Gold nanoparticle (AuNPs) and gold nanopore (AuNPore) catalysts in organic synthesis

BS Takale, M Bao, Y Yamamoto - Organic & Biomolecular Chemistry, 2014 - pubs.rsc.org
Organic synthesis using gold has gained tremendous attention in last few years, especially
heterogeneous gold catalysis based on gold nanoparticles has made its place in almost all …

Single-Atom AuI–N3 Site for Acetylene Hydrochlorination Reaction

Z Chen, Y Chen, S Chao, X Dong, W Chen, J Luo… - Acs …, 2020 - ACS Publications
The gold-catalyzed acetylene hydrochlorination reaction is an important process to produce
vinyl chloride monomer in the polyvinyl chloride industry. The traditional catalyst of carbon …

Highly Selective and Solvent-Dependent Reduction of Nitrobenzene to N-Phenylhydroxylamine, Azoxybenzene, and Aniline Catalyzed by Phosphino-Modified …

S Doherty, JG Knight, T Backhouse, RJ Summers… - ACS …, 2019 - ACS Publications
Gold nanoparticles stabilized by phosphine-decorated polymer immobilized ionic liquids
(AuNP@ PPh2-PIILP) is an extremely efficient multiproduct selective catalyst for the sodium …

A novel, non-metallic graphitic carbon nitride catalyst for acetylene hydrochlorination

X Li, Y Wang, L Kang, M Zhu, B Dai - Journal of catalysis, 2014 - Elsevier
Graphitic carbon nitride (gC 3 N 4) was prepared using a simple method. Activated carbon
(AC) was used to support the gC 3 N 4 catalyst. Catalytic evaluation indicated that the gC 3 …

Descriptors for high-performance nitrogen-doped carbon catalysts in acetylene hydrochlorination

R Lin, SK Kaiser, R Hauert, J Pérez-Ramírez - ACS Catalysis, 2018 - ACS Publications
Nitrogen-doped carbons are promising materials for a broad range of applications.
However, their rational design is greatly hampered by the lack of efficient methods to control …

Non-mercury catalytic acetylene hydrochlorination over bimetallic Au–Co (III)/SAC catalysts for vinyl chloride monomer production

H Zhang, B Dai, X Wang, W Li, Y Han, J Gu… - Green Chemistry, 2013 - pubs.rsc.org
Several gold-based catalysts including Au, Au–La (III), Au–Co (II), and Au–Co (III) were
prepared and assessed for acetylene hydrochlorination, combining with characterizations of …

Self- regeneration of Au/CeO2 based catalysts with enhanced activity and ultra-stability for acetylene hydrochlorination

L Ye, X Duan, S Wu, TS Wu, Y Zhao… - Nature …, 2019 - nature.com
Replacement of Hg with non-toxic Au based catalysts for industrial hydrochlorination of
acetylene to vinyl chloride is urgently required. However Au catalysts suffer from progressive …

Controlling the speciation and reactivity of carbon-supported gold nanostructures for catalysed acetylene hydrochlorination

SK Kaiser, R Lin, S Mitchell, E Fako, F Krumeich… - Chemical …, 2019 - pubs.rsc.org
Carbon-supported gold catalysts have the potential to replace the toxic mercuric chloride-
based system applied industrially for acetylene hydrochlorination, a key technology for the …