Modulation of metal nanocatalysts for enhanced selectivity of chemoselective reduction and addition hydrogenation

X Li, Q Zhang, M Xu, X Li - Molecular Catalysis, 2023 - Elsevier
Selective hydrogenation plays an important role in modern industry. It is an important way to
produce bulk and fine chemical products and intermediates. Among them, selective …

Regulating mesopore structures of support toward enhanced selective hydrogenation of dimethyl oxalate to methyl glycolate on Ag catalysts

Z Luo, X Xu, G Dong, Y Cao, S Hu, G Ye, YA Zhu… - Chemical Engineering …, 2022 - Elsevier
Precisely regulating mesopore structures toward enhanced diffusion of reactants and
targeted product is of great significance for achieving simultaneously improved activity and …

Emerging catalysts for the ambient synthesis of ethylene glycol from CO 2 and its derivatives

R Ye, YY Huang, CC Chen, YG Yao, M Fan… - Chemical …, 2023 - pubs.rsc.org
Ethylene glycol (EG), a useful chemical raw material, has been widely applied in many
aspects of modern society. The conventional preparation of ethylene glycol mainly uses the …

Rational design of hydroxyapatite/graphite-supported bimetallic Cu–M (M= Cu, Fe, Co, Ni) catalysts for enhancing the partial hydrogenation of dimethyl oxalate to …

M Abbas, JM Wang, P Stelmachowski… - Catalysis Science & …, 2023 - pubs.rsc.org
In the sequential hydrogenation reaction of dimethyl oxalate (DMO→ MG→ EG→ EtOH), the
control of product distribution to methyl glycolate (MG) is challenging, therefore noble metal …

A promising alternative potential solution for sustainable and economical development of coal to ethylene glycol industry: Dimethyl oxalate to methyl glycolate process

Q Yang, Y Fan, C Liu, J Zhou, L Zhao, H Zhou - Energy, 2023 - Elsevier
The rapid expansion of coal-to-ethylene glycol (CtEG) industry leads to an oversupply of
ethylene glycol and poor economic performance. Dimethyl oxalate is an important …

Insights into support effects of Ag/SiO2 catalysts for dimethyl glycolate semi-hydrogenation to methyl glycolate

Z Luo, Y Shen, D Fang, C He, Y Cao, W Li, YA Zhu… - Molecular …, 2024 - Elsevier
Support materials play vital roles in heterogenous catalysis via the so-called support effects,
and understanding on the support effects is beneficial for the design of high-performance …

Highly stable Cu catalyst embedded in N-doped carbon microsphere for hydrogenation of dimethyl oxalate to methyl glycolate

H Zhang, Y Song, S Wu, S Yin, J Zhao, J Ren - Applied Catalysis A …, 2024 - Elsevier
Cu catalyst often subjects to low stability due to chemical state transformation during carbon-
oxygen hydrogenation reaction. In the present work, the copper catalysts embedded in N …

Selective Hydrogenation of Dimethyl Oxalate to Methyl Glycolate over Boron-Modified Ag/SiO2 Catalysts

S Cheng, T Meng, D Mao, X Guo, J Yu - ACS omega, 2022 - ACS Publications
The addition of boron (B) as a promoter to the Ag/SiO2 catalyst for the selective
hydrogenation of dimethyl oxalate (DMO) to methyl glycolate (MG) was investigated. A …

[PDF][PDF] 草酸二甲酯加氢制乙醇酸甲酯反应网络分析及其多相加氢催化剂研究进展

张大洲, 卢文新, 商宽祥, 胡媛, 朱凡, 张宗飞 - 化工进展, 2023 - hgjz.cip.com.cn
乙醇酸甲酯(MG) 官能团丰富, 是一种重要的精细化工中间体, 而且经过缩聚反应可制得新一代可
生物降解材料聚乙醇酸. 采用合成气经草酸二甲酯(DMO) 加氢路线可实现MG 的规模化制备 …

Modulation of supported Ni catalysts with phosphorus for the hydrogenation of diethyl oxalate to ethyl glycolate

Q Xue, Z Jiang, C Wang, X Kan, J Wang… - New Journal of …, 2024 - pubs.rsc.org
In this study, 13-Ni/ZrO2, 13-Ni3P/ZrO2, 13-Ni/SiO2, and 13-Ni3P/SiO2 catalysts were used
in the hydrogenation of diethyl oxalate (DEO) to ethyl glycolate (Egly) to investigate the …