Nanooptomechanical Transduction in a Single Crystal with 100% Photoconversion

JM Cole, DJ Gosztola… - The Journal of Physical …, 2021 - ACS Publications
Materials that exhibit nanooptomechanical transduction in their single-crystal form have
prospective use in light-driven molecular machinery, nanotechnology, and quantum …

[HTML][HTML] Rapid build up of nanooptomechanical transduction in single crystals of a ruthenium-based SO 2 linkage photoisomer

JM Cole, DJ Gosztola, JJ Velazquez-Garcia… - Chemical …, 2021 - pubs.rsc.org
Single-crystal nanooptomechanical transduction occurs in [Ru (SO2)(NH3) 4 (H2O)]
chlorobenzenesulfonate2, reaching maximal levels within 40 s at 100 K when …

Structural Capture of η1-OSO to η2-(OS)O Coordination Isomerism in a New Ruthenium-Based SO2-Linkage Photoisomer That Exhibits Single-Crystal Optical …

JM Cole, DJ Gosztola… - The Journal of Physical …, 2022 - ACS Publications
Recent discoveries of a range of single-crystal optical actuators are feeding a new form of
materials chemistry, given their broad range of potential applications, from light-induced …

Single-Crystal Optical Actuation Generated by 100% SO2 Linkage Photoisomerization in a Ruthenium-Based Coordination Complex

JM Cole, DJ Gosztola… - The Journal of …, 2021 - ACS Publications
Single-crystal optical actuators are emerging as a new field of materials chemistry because
of their wide-ranging potential applications, from light-induced molecular motors to …

Light-induced macroscopic peeling of single crystal driven by photoisomeric nano-optical switching

JM Cole, JJ Velazquez-Garcia, DJ Gosztola… - Chemistry of …, 2019 - ACS Publications
Single-crystal optical actuators are emerging as a prospective material form for nano-optical
mechanical switching, sensing, or transduction device applications in nanotechnology and …

SO2 phototriggered crystalline nanomechanical transduction of aromatic rotors in tosylates: Rationalization via photocrystallography of [Ru (NH3) 4SO2X] tosylate2 (X …

SO Sylvester, JM Cole, PG Waddell… - The Journal of …, 2014 - ACS Publications
Thermally reversible solid-state linkage SO2 photoisomers of three complexes in the [Ru
(NH3) 4SO2 X] tosylate2 family are captured in their metastable states using …

Assigning Optical Absorption Transitions with Light-Induced Crystal Structures: Case Study of a Single-Crystal Nanooptomechanical Transducer

JM Cole, DJ Gosztola, SO Sylvester… - The Journal of …, 2021 - ACS Publications
UV/vis absorption spectroscopy affords indirect structural information about the
photochemistry and photophysics of molecules by inferring types of electronic transitions …

[HTML][HTML] Low-energy optical switching of SO 2 linkage isomerisation in single crystals of a ruthenium-based coordination complex

JM Cole, DJ Gosztola, SO Sylvester - RSC advances, 2021 - pubs.rsc.org
Single crystals that behave as optical switches are desirable for a wide range of
applications, from optical sensors to read–write memory media. A series of ruthenium-based …

Photochemistry: Solar‐Powered Nanomechanical Transduction from Crystalline Molecular Rotors (Adv. Mater. 24/2013)

SO Sylvester, JM Cole - Advanced Materials, 2013 - infona.pl
The back cover displays the futuristic application of molecular motors within an all‐optical
circuitry. On page 3324, Jacqueline M. Cole and Sven O. Sylvester demonstrate …

Systems Approach of Photoisomerization Metrology for Single-Crystal Optical Actuators: A Case Study of [Ru(SO2)(NH3)4Cl]Cl

JM Cole, DJ Gosztola… - The Journal of …, 2020 - ACS Publications
Chemicals that undergo photoisomerization in their single-crystal form may act as optical
actuators or sensors. It is important to determine the molecular-scale characteristics of this …