Design of ultrastiff organosilicate hybrid glasses

KI Kilic, RH Dauskardt - Advanced Functional Materials, 2019 - Wiley Online Library
Hyperconnected hybrid organosilicate glass networks formed by hyperstiff precursor
molecules with certain geometrical characteristics can lead to exceptional elastic properties …

Hyperconnected molecular glass network architectures with exceptional elastic properties

JA Burg, MS Oliver, TJ Frot, M Sherwood, V Lee… - Nature …, 2017 - nature.com
Hyperconnected network architectures can endow nanomaterials with remarkable
mechanical properties that are fundamentally controlled by designing connectivity into the …

Mechanically reliable hybrid organosilicate glasses for advanced interconnects

KI Kilic, RH Dauskardt - Journal of Vacuum Science & Technology B, 2020 - pubs.aip.org
We explore the structure–property relationships in hybrid organosilicate glasses that form a
special class of materials for use in advanced interconnects to improve their mechanical …

Molecular origins of the mechanical behavior of hybrid glasses

MS Oliver, G Dubois, M Sherwood… - Advanced Functional …, 2010 - Wiley Online Library
Hybrid organic‐inorganic glasses exhibit unique electro‐optical properties along with
excellent thermal stability. Their inherently mechanically fragile nature, however, which …

Stiffening of organosilicate glasses by organic cross-linking

H Li, JM Knaup, E Kaxiras, JJ Vlassak - Acta Materialia, 2011 - Elsevier
Atomistic simulations show that organosilicates, used as low permittivity dielectric materials
in advanced integrated circuits, can be made substantially stiffer than amorphous silica …

Molecular design of ultra-low-k hybrid glasses

M Oliver, G Dubois, R Dauskardt - 2010 IEEE International …, 2010 - ieeexplore.ieee.org
Bridged organosilicates have recently emerged as potential ultra-low-k (ULK) candidates for
the 32 nm technology node and beyond due to their superior mechanical properties. While …

Tailoring structure and properties of silica glass aided by computer simulation

L Huang, F Yuan, M Guerette, Q Zhao… - Journal of Materials …, 2017 - cambridge.org
By using a combination of experiments and molecular dynamics simulations, our studies
show that the elastic response of silica glass to initial compression gradually changes from …

Star alkoxysilane molecules, gels and appreciably tough glasses

KG Sharp - Journal of Materials Chemistry, 2005 - pubs.rsc.org
A family of hybrid organic–inorganic network materials—the star gels and glasses—has
been synthesized from highly functional poly (alkoxysilane) molecular precursors. The …

Structure and topology of soda-lime silicate glasses: implications for window glass

O Laurent, B Mantisi, M Micoulaut - The Journal of Physical …, 2014 - ACS Publications
The structural and topological properties of soda-lime silicate glasses of the form (1–2 x)
SiO2–x Na2O–x CaO are studied from classical molecular dynamics using a Buckingham …

A New Route to Polymer-Filled Glass: Hybrid Interpenetrating Networks with Appreciable Toughness

KG Sharp - 1995 - ACS Publications
Hybrid inorganic/organic materials can be generated in non-aqueous systems by rapid
formation of polysilicate networks in the presence of dissolved organic polymers. The …