Plasma atomic layer etching for titanium nitride at low temperatures

D Shim, J Kim, Y Kim, H Chae - … of Vacuum Science & Technology B, 2022 - pubs.aip.org
Isotropic plasma atomic layer etching (ALE) was developed for titanium nitride (TiN) through
a three-step process: plasma oxidation, plasma fluorination, and thermal removal at low …

Atomic layer etching of titanium nitride with surface modification by Cl radicals and rapid thermal annealing

N Miyoshi, N McDowell, H Kobayashi - Journal of Vacuum Science & …, 2022 - pubs.aip.org
Thermal atomic layer etching (ALE) is a promising method for isotropic etching with atomic
level precision and high conformality over three-dimensional structures. In this study, a …

Rapid thermal-cyclic atomic-layer etching of titanium nitride in CHF3/O2 downstream plasma

K Shinoda, N Miyoshi, H Kobayashi… - Journal of Physics D …, 2019 - iopscience.iop.org
Isotropic atomic-layer etching (ALE) of TiN—by using a plasma-assisted thermal-cyclic
process with a 300-mm tool—was demonstrated. The process consists of exposure to a …

Remote plasma etching of titanium nitride using NF3/argon and chlorine mixtures for chamber clean applications

R Hellriegel, M Albert, B Hintze, H Winzig… - Microelectronic …, 2007 - Elsevier
To avoid plasma induced erosion of chamber hardware, the application of remote plasma
sources to activate the etch gases was introduced. We present results on the etch behaviour …

Tantalum etching with a nonthermal atmospheric-pressure plasma

VJ Tu, JY Jeong, A Schütze, SE Babayan… - Journal of Vacuum …, 2000 - pubs.aip.org
Tantalum was etched in a downstream, atmospheric-pressure plasma. In this process,
etching occurred without significant ion bombardment. An etching rate of 6.0±0.5 μm/min …

Atomic layer etching of Al2O3 with NF3 plasma fluorination and trimethylaluminum ligand exchange

J Kim, D Shim, Y Kim, H Chae - … of Vacuum Science & Technology A, 2022 - pubs.aip.org
In this study, a cyclic isotropic plasma atomic layer etching (ALE) process was developed for
aluminum oxide that involves fluorination with NF 3 plasma and ligand exchange with …

Selective atomic layer etching of Al2O3, AlNx and HfO2 in conventional ICP etching tool

V Kuzmenko, Y Lebedinskij, A Miakonkikh, K Rudenko - Vacuum, 2023 - Elsevier
The atomic layer etching process of Al 2 O 3, AlN x and HfO 2 in conventional plasma
etching tool was investigated. The etching process is based on surface modification by …

Surface reaction during thermal atomic layer etching of aluminum oxide films using fluorine radicals and trimethylaluminum

Y Kim, O Kim, G Cho, HL Kim, M Kim, B Cho… - Applied Surface …, 2023 - Elsevier
We investigated the surface reaction of the thermal atomic layer etching (ALE) of Al 2 O 3
film using fluorine (F) radicals and trimethylaluminum (TMA). As a strong fluorination source …

Thermal Atomic Layer Etching of Titanium Nitride Using Sequential, Self-Limiting Reactions: Oxidation to TiO2 and Fluorination to Volatile TiF4

Y Lee, SM George - Chemistry of Materials, 2017 - ACS Publications
The thermal atomic layer etching (ALE) of TiN was demonstrated using a new etching
mechanism based on sequential, self-limiting oxidation and fluorination reactions. The …

Quasi-atomic layer etching of silicon nitride

SD Sherpa, A Ranjan - Journal of Vacuum Science & Technology A, 2017 - pubs.aip.org
Atomic layer etching (ALE) is a promising technique that can solve the challenges
associated with continuous or pulsed plasma processes—trade-offs between selectivity …