V and V–P containing Zr-SBA-15 catalysts for dehydration of glycerol to acrolein

JA Cecilia, C García-Sancho, JM Mérida-Robles… - Catalysis Today, 2015 - Elsevier
A series of solid acid catalysts based on vanadium and vanadium–phosphorous supported
on a zirconium doped mesoporous SBA-15 silica has been synthesized, characterized by …

WO3 supported on Zr doped mesoporous SBA-15 silica for glycerol dehydration to acrolein

JA Cecilia, C García-Sancho, JM Mérida-Robles… - Applied Catalysis A …, 2016 - Elsevier
Glycerol dehydration to acrolein is one of the most promising routes to valorize the surplus of
such by-product of the biodiesel industry. In this context, a family of solid acid catalysts …

Aluminum doped mesoporous silica SBA-15 for glycerol dehydration to value-added chemicals

JA Cecilia, C García-Sancho, JM Mérida-Robles… - Journal of Sol-Gel …, 2017 - Springer
A series of Al-grafted mesoporous SBA-15 silica was synthesized and tested as catalysts in
the gas-phase dehydration of glycerol to acrolein. Different Si/Al molar ratios were employed …

Sulfonic-functionalized SBA-15 as an active catalyst for the gas-phase dehydration of glycerol

JP Lourenço, MI Macedo, A Fernandes - Catalysis Communications, 2012 - Elsevier
Sulfonic-functionalized mesoporous silicas (SBA-15) were used as catalysts in the gas-
phase dehydration of glycerol at moderate temperature (275 and 300° C). For the tested …

Solid acid catalysts for dehydration of glycerol to acrolein in gas phase

E Kraleva, R Palcheva, L Dimitrov, U Armbruster… - Journal of materials …, 2011 - Springer
The reaction of glycerol dehydration to acrolein was performed at temperatures 220–300° C
over Keggin-type heteropolyacid (H 3 PW 12 O 40· x H 2 O), supported on alumina and W …

Zirconium doped mesoporous silica catalysts for dehydration of glycerol to high added-value products

C García-Sancho, R Moreno-Tost… - Applied Catalysis A …, 2012 - Elsevier
A series of zirconium doped mesoporous silica, with different Si/Zr molar ratios, has been
synthesized and tested in the gas-phase dehydration of glycerol. The surface …

Influence of the niobium supported species on the catalytic dehydration of glycerol to acrolein

C García-Sancho, JA Cecilia, A Moreno-Ruiz… - Applied Catalysis B …, 2015 - Elsevier
The present work deals with the catalytic performance of a series of supported niobium
oxide (1–12 wt% Nb 2 O 5) catalysts in the gas phase dehydration of glycerol. The niobium …

Sulfonic functionalized SBA-15 catalysts in the gas phase glycerol dehydration. Thermal stability and catalyst deactivation

BO Dalla Costa, MS Legnoverde, C Lago… - Microporous and …, 2016 - Elsevier
The catalytic conversion of glycerol to acrolein was studied using sulfonic functionalized
mesoporous silica SBA-15. The catalysts were prepared by the co-condensation method …

Catalytic dehydration of glycerol to acrolein over HPW supported on Cs+ modified SBA-15

R Liu, T Wang, Y Jin - Catalysis Today, 2014 - Elsevier
The sustainable production of acrolein from glycerol dehydration is a competitive alternative
to the propylene-based technology. A new catalyst, H 3 PW 12 O 40 supported on Cs+ …

Toward longer life catalysts for dehydration of glycerol to acrolein

R Znaiguia, L Brandhorst, N Christin, VB Baca… - Microporous and …, 2014 - Elsevier
In this work, tungstated zirconias were prepared by different methods and evaluated for
glycerol dehydration to acrolein. For all the tested catalysts, the absence of crystalline WO 3 …