Radical selenylative cyclization of trifluoromethyl propargyl imines for the synthesis of trifluoromethyl-and seleno-azaspiro [4, 5]-tetraenones and quinolines

G Wei, J Zhang, H Wang, Z Chen, XF Wu - Organic & Biomolecular …, 2023 - pubs.rsc.org
A radical selenylative cyclization of trifluoromethyl propargyl imines with diselenides for the
regiodivergent construction of diversely functionalized azaspiro [4, 5]-tetraenones and …

Metal-free switchable ortho/ipso-cyclization of N-aryl alkynamides: divergent synthesis of 3-selenyl quinolin-2-ones and azaspiro [4, 5] trienones

H Sahoo, GS Grandhi, I Ramakrishna… - Organic & Biomolecular …, 2019 - pubs.rsc.org
A selenium radical triggered switchable ortho/ipso-cyclization cascade of N-aryl
alkynamides has been devised under metal-free conditions to access 3-selenyl quinolin-2 …

Selectfluor-mediated construction of 3-arylselenenyl and 3, 4-bisarylselenenyl spiro [4.5] trienones via cascade annulation of N-phenylpropiolamides with diselenides

JW Yuan, Q Chen, WT Wu, JJ Zhao, LR Yang… - New Journal of …, 2022 - pubs.rsc.org
A cascade annulation of terminal alkynyl amides with diselenides leading to the construction
of 3-arylselenenyl spiro [4.5] trienones was realized under mild conditions with Selectfluor …

Visible light-induced selenylative spirocyclization of biaryl ynones toward the formation of selenated spiro [5.5] trienones

Z Chen, X Zheng, SF Zhou, X Cui - Organic & Biomolecular Chemistry, 2022 - pubs.rsc.org
A visible-light induced dearomative cascade cyclization of biaryl ynones with diselenides
under photocatalyst and external additive-free conditions has been explored, giving a series …

K2S2O8‐induced Dearomative Spirocyclization of Biaryl Ynones with Diselenides toward Selenated Spiro[5.5]trienones

L Yu, Y Peng - Asian Journal of Organic Chemistry, 2023 - Wiley Online Library
A metal‐free radical spirocyclization of biaryl ynones with diselenides is developed,
providing selenated spiro [5.5] trienones in moderate to good yields. This protocol features …

Selenium radical mediated cascade cyclization: concise synthesis of selenated benzofurans (benzothiophenes)

C An, CY Li, XB Huang, WX Gao, YB Zhou, MC Liu… - Organic …, 2019 - ACS Publications
Presented in this work is a novel methodology for the synthesis of selenated benzofurans (or
benzothiophenes) via AgNO2-catalyzed radical cyclization of 2-alkynylanisoles (or 2 …

Synthesis of 3‐Organoselenyl‐2H‐Coumarins from Propargylic Aryl Ethers via Oxidative Radical Cyclization

JD Fang, XB Yan, L Zhou, YZ Wang… - Advanced Synthesis & …, 2019 - Wiley Online Library
A metal‐free oxidative radical cyclization/selenylation of propargylic aryl ethers with diaryl
diselenides was developed. This protocol provided an alternative method to synthesize 3 …

Chalcogenative spirocyclization of N-aryl propiolamides with diselenides/disulfides promoted by Selectfluor

JW Yuan, GC Huang, LL Wang, XY Wang… - … für Naturforschung B, 2022 - degruyter.com
A practical and efficient synthetic route to construct a variety of 3-arylselenenyl/3-arylthio
spiro [4.5] trienones was developed using Selectfluor reagent as a mild oxidant. This …

Synthesis of Seleno-Dibenzocycloheptenones/Spiro [5.5] Trienones by Radical Cyclization of Biaryl Ynones

HA Goulart, RH Bartz, TJ Peglow… - The Journal of …, 2022 - ACS Publications
We report herein an alternative method for the synthesis of seleno-dibenzocycloheptenones
and seleno-spiro [5.5] trienones through the radical cyclization of biaryl ynones in the …

Potassium tert-Butoxide-Promoted Tandem Cyclization of Organoselenium Alkynyl Aryl Propargyl Ethers

R do Carmo Pinheiro, DF Back, SG Muller… - The Journal of …, 2022 - ACS Publications
Base-promoted cyclization of 3-organoselenyl-methylene-2-alkynyl aryl propargyl ethers
has been developed for the synthesis of 3-butylselanyl-methylene benzofurans, 3-methyl-2 …