Template-based approaches to the preparation of amorphous, nanoporous silicas

NK Raman, MT Anderson, CJ Brinker - Chemistry of Materials, 1996 - ACS Publications
This review discusses two classes of organic template-derived amorphous silicas
distinguished by the nature of template-matrix interactions and the extent to which …

A non‐surfactant templating route to mesoporous silica materials

Y Wei, D Jin, T Ding, WH Shih, X Liu… - Advanced …, 1998 - Wiley Online Library
The templated synthesis of mesoporous materials using surfactant templates has been
known since 1992. The discovery reported here, that non‐surfactant organic molecules, eg …

Synthesis of ordered and disordered silicas with uniform pores on the border between micropore and mesopore regions using short double-chain surfactants

R Ryoo, IS Park, S Jun, CW Lee, M Kruk… - Journal of the …, 2001 - ACS Publications
Silica molecular sieves with uniform pores on the borderline between micropore (diameter<
2 nm) and mesopore (from 2 to 50 nm) ranges were synthesized by a novel method using …

Direct synthesis of hybrid organic− inorganic nanoporous silica by a neutral amine assembly route: structure− function control by stoichiometric incorporation of …

L Mercier, TJ Pinnavaia - Chemistry of Materials, 2000 - ACS Publications
The co-condensation of tetraethoxysilane (TEOS) and organotrialkoxysilane molecules by
neutral alkylamine surfactant assembly (S0I0) is a convenient synthesis methodology for the …

Microporous silica prepared by organic templating: relationship between the molecular template and pore structure

Y Lu, G Cao, RP Kale, S Prabakar, GP López… - Chemistry of …, 1999 - ACS Publications
Microporous silica materials with a controlled pore size and a narrow pore size distribution
have been prepared by sol− gel processing using an organic-templating approach …

A novel anionic surfactant templating route for synthesizing mesoporous silica with unique structure

S Che, AE Garcia-Bennett, T Yokoi, K Sakamoto… - Nature materials, 2003 - nature.com
Anionic surfactants are used in greater volume than any other surfactants because of their
highly potent detergency and low cost of manufacture. However, they have not been used as …

Metamorphosis of ordered mesopores to micropores: periodic silica with unprecedented loading of pendant reactive organic groups transforms to periodic …

M Kruk, T Asefa, M Jaroniec… - Journal of the American …, 2002 - ACS Publications
Ordered porous silicas with unprecedented loadings of pendant vinyl groups have been
synthesized via co-condensation of tetraethyl orthosilicate (TEOS) and triethoxyvinylsilane …

Synthesis of hybrid inorganic–organic mesoporous silica by co-condensation of siloxane and organosiloxane precursors

SL Burkett, SD Sims, S Mann - Chemical Communications, 1996 - pubs.rsc.org
Organically functionalized mesoporous silicas are prepared at room temperature by the co-
condensation of tetraethoxysilane and organosiloxanes in the presence of surfactant …

Sugar-modified silanes: precursors for silica monoliths

MA Brook, Y Chen, K Guo, Z Zhang… - Journal of Materials …, 2004 - pubs.rsc.org
Sugarsilanes, alkoxysilanes derived from sugars and sugar alcohols including glycerol,
sorbitol, maltose and dextran, were hydrolyzed to prepare monolithic, mesoporous silicas …

Structural and morphological control of cationic surfactant-templated mesoporous silica

HP Lin, CY Mou - Accounts of Chemical Research, 2002 - ACS Publications
Micelle-templated mesoporous silica materials are rapidly becoming important in many
fields of chemistry for hosting reactants or catalysts in confined space. Fine control of the …