Mechanical properties and swelling behavior of end-linked poly (diethylsiloxane) networks

RC Hedden, H Saxena, C Cohen - Macromolecules, 2000 - ACS Publications
Linear α, ω-vinyl-terminated poly (diethylsiloxane)(PDES) chains were synthesized and
fractionated to obtain melts of low polydispersity. The fractionated samples were …

Elastomeric properties of end-linked networks of high cross-link functionality. Accounting for possible changes in effective functionality with extent of reaction and …

MA Sharaf, JE Mark, E Ahmed - Colloid and Polymer Science, 1994 - Springer
This study reanalyzes some elastomeric properties in elongation reported for poly
(dimethylsiloxane)(PDMS) networks of high cross-link functionality which had been …

Dynamic mechanical losses in filled poly (dimethylsiloxane) networks

MA Sharaf, A Kloczkowski… - Rubber Chemistry and …, 1995 - meridian.allenpress.com
This investigation focused on the study of dynamic mechanical losses in silica-filled
networks of poly (dimethylsiloxane)(PDMS). Some of the samples were filled using a novel …

Interpenetrating polymer networks of poly (dimethylsiloxane): 1. Preparation and characterization

EE Hamurcu, BM Baysal - Polymer, 1993 - Elsevier
Abstract Model networks of α, ω-dihydroxy-poly (dimethylsiloxane)(PDMS) were prepared by
tetrafunctional crosslinking agent tetraethyl orthosilicate (TEOS) and the catalyst stannous 2 …

Segmental relaxation in end-linked poly (dimethylsiloxane) networks

MJ Schroeder, CM Roland - Macromolecules, 2002 - ACS Publications
End-linked polydimethysiloxane (PDMS) networks were prepared by end-linking vinyl-
terminated PDMS chains with tetrafunctional silanes. Dielectric α-relaxation spectra, thermal …

Unidirectional compression measurements on swollen polydimethylsiloxane networks

A Belkebir-Mrani, G Beinert, J Herz, P Rempp - European Polymer Journal, 1977 - Elsevier
Polydimethylsiloxane model-networks were prepared by the endlinking reaction of α, ω-
functional polydimethylsiloxane precursor polymers with 3, 4 and 6 functional compounds …

Elastomeric networks cross-linked by silica or titania fillers

GS Sur, JE Mark - European polymer journal, 1985 - Elsevier
Abstract Triethoxysilyl-terminated poly (dimethylsiloxane)(PDMS) was prepared by reacting
triethoxysilane with vinyl-terminated PDMS having a number-average molecular weight of …

Effect of network structure on the stress–strain behaviour of endlinked PDMS elastomers

SH Yoo, L Yee, C Cohen - Polymer, 2010 - Elsevier
Endlinked poly (dimethylsiloxane)(PDMS) networks synthesized from telechelic precursor
chains of different molar mass were prepared with varying volume fractions of non-reactive …

Tensile and swelling behavior of model silicone networks with low extents of cross-linking

KA Kirk, SA Bidstrup, EW Merrill, KO Meyers - Macromolecules, 1982 - ACS Publications
Multifunctional elastomeric networks of known network chain density, vj V, were prepared by
end-linking a, co-divinyl-poly (dimethylsiloxane)(,-divinyl-PDMS) chains ranging in number …

Model networks of end‐linked polydimethylsiloxane chains. XII. Dependence of ultimate properties on dangling‐chain irregularities

AL Andrady, MA Llorente, MA Sharaf… - Journal of Applied …, 1981 - Wiley Online Library
Elastomeric networks were prepared by end‐linking vinyl‐terminated polydimethylsiloxane
(PDMS) chains having number‐average molecular weights of 11.3× 103 g mol− 1. The tetra …