Comparison of Eco-friendly Ti–M Bimetallic Coordination Catalysts and Commercial Monometallic Sb- or Ti-Based Catalysts for the Synthesis of Poly(ethylene-co …

S Xie, S Qian, K Zhu, L Sun, W Chen, S Chen - ACS omega, 2023 - ACS Publications
Sustainable development greatly benefits from the effective synthesis of bio-based
copolymers that are environmentally friendly. To enhance the polymerization reactivity for …

[HTML][HTML] Bimetallic Catalytic Systems Based on Sb, Ge and Ti for the Synthesis of Poly(ethylene terephthalate-co-isosorbide terephthalate)

N Stanley, T Chenal, T Delaunay, R Saint-Loup… - Polymers, 2017 - mdpi.com
The insertion of rigid monomers such as isosorbide into poly (ethylene terephthalate)(PET)
allows for the access of polymers with improved properties, notably in terms of thermal …

Catalytic property of poly (ethylene terephthalate-co-isophthalate) synthesized with a novel Sb/Al bimetallic compound catalyst

F Zhang, H Kang, Y Bai, B Jiang, Y Huang, L Liu - RSC advances, 2016 - pubs.rsc.org
In this paper, the hydrolysis process of aluminum subacetate (AlSA) was studied by Fourier
transform infrared (FT-IR), 27Al nuclear magnetic resonance (NMR), X-ray diffraction (XRD) …

Designing hydrolysis-resistant Ti/Zn bimetallic catalyst based on the coordination activation mechanism to synthesize high molecular weight poly (1, 5-pentene …

W Shen, C Xu, C Zeng, Y Yu, S Zhang, P Ji, H Wang - Polymer, 2024 - Elsevier
The high molecular weight poly (1, 5-pentene terephthalate) synthesis and its molecular
weight distribution control are still challenging, and one of the critical problems is the lack of …

[HTML][HTML] Poly (ethylene terephthalate-co-isophthalate) synthesized via a Sb/Al bimetallic compound catalyst: the effect of the end groups on the properties of polyester

F Zhang, Q Wang, L Wang, Y Bai - RSC advances, 2017 - pubs.rsc.org
Herein, poly (ethylene terephthalate-co-isophthalate)(PETI) was synthesized via an ethylene
glycol stibium/γ-AlOOH composite catalyst and a study was carried out on the structural …

Efficiency Increase of Poly(ethylene terephthalate‐co‐isosorbide terephthalate) Synthesis using Bimetallic Catalytic Systems

JC Bersot, N Jacquel, R Saint‐Loup… - Macromolecular …, 2011 - Wiley Online Library
New catalytic systems are developed to increase the transesterification efficiency during the
synthesis of poly (ethylene terephthalate‐co‐isosorbide terephthalate) with the aim of …

Novel catalysts based on titanium dioxide/silicon dioxide for poly (ethylene terephthalate)

M Yin, C Li, G Guan, D Zhang… - Journal of applied polymer …, 2010 - Wiley Online Library
A series of titanium dioxide/silicon dioxide based poly (ethylene terephthalate)(PET)
polycondensation catalysts were synthesized with different Si/Ti molar ratios and various …

UiO-66 (Zr/Ti) for catalytic PET polycondensation

J Wang, S Zhang, Y Han, L Zhang, Q Wang, G Wang… - Molecular …, 2022 - Elsevier
Abstract PET (poly (ethylene terephthalate)) is one of the most important type of
thermoplastic polyesters and widely used in various fields. Titanium-based catalysts are …

Organocatalysts for the Synthesis of Poly(ethylene terephthalate‐co‐isosorbide terephthalate): A Combined Experimental and DFT Study

N Stanley, T Chenal, N Jacquel… - Macromolecular …, 2019 - Wiley Online Library
Organocatalysts are assessed for the insertion of isosorbide, a rigid, biobased diol
monomer, into poly (ethylene terephthalate). A sulfonic acid (p‐toluenesulfonic acid …

Ethylene glycol-soluble Ti/Mg-citrate complex catalyst for synthesis of high intrinsic viscosity poly (ethylene terephthalate)

Q Lin, F Gao, Y Wang, W Lu, W Chen - Polymer, 2022 - Elsevier
Antimony-free poly (ethylene terephthalate)(PET) has been synthesized through
polycondensation of p-phthalic acid and ethylene glycol, and then subjected to a viscosity …