How to maximize birefringence and nonlinearity of π-conjugated cyanurates

J Lu, YK Lian, L Xiong, QR Wu, M Zhao… - Journal of the …, 2019 - ACS Publications
Materials with large birefringence (Δ n) are highly needed by fiber-optic isolators, whereas
crystals showing strong second-order harmonic generation (SHG) are the key component for …

Cyanurates consisting of intrinsic planar π-conjugated 6-membered rings: An emerging source of optical functional materials

X Meng, W Yin, M Xia - Coordination Chemistry Reviews, 2021 - Elsevier
Optical crystalline materials, particularly for linear birefringent crystals and non-linear optical
(NLO) crystal materials, play an incredible role in opto-electronics, laser industry and …

Perfectly Encoding π‐Conjugated Anions in the RE5(C3N3O3)(OH)12 (RE=Y, Yb, Lu) Family with Strong Second Harmonic Generation Response and …

X Meng, X Zhang, Q Liu, Z Zhou, X Jiang… - Angewandte …, 2023 - Wiley Online Library
Nonlinear optical (NLO) crystal, which simultaneously exhibits strong second‐harmonic‐
generation (SHG) response and desired optical anisotropy, is a core optical material …

KLi(HC3N3O3)·2H2O: Solvent-drop Grinding Method toward the Hydro-isocyanurate Nonlinear Optical Crystal

D Lin, M Luo, C Lin, F Xu, N Ye - Journal of the American …, 2019 - ACS Publications
A novel mixed alkali hydro-isocyanurate, KLi (HC3N3O3)· 2H2O was first prepared in AOH-
BOH-H3C3N3O3 (A/B= Li/Na/K/Rb/Cs) system via a solvent-drop grinding method. KLi …

Molecular Construction Using (C3N3O3)3– Anions: Analysis and Prospect for Inorganic Metal Cyanurates Nonlinear Optical Materials

F Liang, L Kang, X Zhang, MH Lee, Z Lin… - Crystal Growth & …, 2017 - ACS Publications
Molecular construction using good optically active microscopic units is vital to efficiently
explore good nonlinear optical (NLO) materials, a type of important optoelectronic functional …

A High‐Performance Nonlinear Optical Crystal with a Building Block Containing Expanded π‐Delocalization

Y Li, W Huang, Y Zhou, X Song, J Zheng… - Angewandte Chemie …, 2023 - Wiley Online Library
Common nonlinear optical (NLO) crystals consist of traditional functional building blocks
with inherent optical limitation. Herein, inspired by traditional (B3O6) 3− inorganic building …

K3C6N7O3·2H2O: A Multifunctional Nonlinear Optical Cyamelurate Crystal with Colossal π-Conjugated Orbitals

X Zhang, X Du, J Wang, F Wang, F Liang… - … Applied Materials & …, 2022 - ACS Publications
The delocalized π-conjugated units are considered as an advantageous gene for improving
the optical nonlinearity of acentric crystals. For the first time, we synthesized a new acentric …

Ba 2 M (C 3 N 3 O 3) 2 (M= Mg, Ca): potential UV birefringent materials with strengthened optical anisotropy originating from the (C 3 N 3 O 3) 3− group

Z Li, F Liang, Y Guo, Z Lin, J Yao, G Zhang… - Journal of Materials …, 2018 - pubs.rsc.org
Demands for UV birefringent materials are growing dramatically owing to the rapid
development of ultraviolet technology. Here, a new family of UV birefringent materials …

Finding the First Squarates Nonlinear Optical Crystal NaHC4O4·H2O with Strong Second Harmonic Generation and Giant Birefringence

X Zhang, D Cao, D Yang, Y Wang, K Wu… - ACS Materials …, 2022 - ACS Publications
With the development of laser technology, nonlinear optical (NLO) crystals with optimal
performance are urgently required. Finding new NLO-active units is necessary to expand the …

Remarkable NLO response and infrared absorption in simple twisted molecular π-chromophores

IDL Albert, TJ Marks, MA Ratner - Journal of the American …, 1998 - ACS Publications
Computational modeling reveals that, by substitutional modification of interplanar dihedral
angles in a series of quinopyrans, both the optical absorption cross section and the first …