Fashioning microporous covalent organic frameworks (COFs) into single crystals with
ordered macropores allows for an effective reduction of the mass transfer resistance and the …

Abstract Constructing three‐dimensional (3D) structural characteristics on two‐dimensional
(2D) covalent organic frameworks (COFs) is a good approach to effectively improve the …

Partitioning the pores of covalent organic frameworks (COFs) is an attractive strategy for
introducing microporosity and achieving new functionality, but it is technically challenging to …

Conspectus Porous organic framework materials constructed by periodically aligned
molecular entities offer chemically tailored microenvironments to absorb molecules and ions …

The effective control of crystallinity of covalent organic frameworks (COFs) and the
optimization of their performances related to the crystallinity have been considered as big …

Although isomerism is a typical and significant phenomenon in organic chemistry, it is rarely
found in covalent organic framework (COF) materials. Herein, for the first time, we report a …

Two 2-dimensional covalent organic frameworks (COFs; TJNU-203 and TJNU-204) with
high crystallinity and large specific surface area are rationally fabricated using a three …

Ionic covalent organic frameworks (iCOFs), a subclass of COFs, offer a functional platform
for diverse applications. However, strong charge repulsion between adjacent layers often …

Pore environment and aggregated structure play a vital role in determining the properties of
porous materials, especially regarding the mass transfer. Reticular chemistry imparts …

The development of three-dimensional (3D) covalent organic frameworks (COFs) with large
pores and high surface areas is of great importance for various applications. However, it …