Boosting CO hydrogenation towards C2+ hydrocarbons over interfacial TiO2−x/Ni catalysts

M Xu, X Qin, Y Xu, X Zhang, L Zheng, JX Liu… - Nature …, 2022 - nature.com
Considerable attention has been drawn to tune the geometric and electronic structure of
interfacial catalysts via modulating strong metal-support interactions (SMSI). Herein, we …

Structure Sensitivity of CO2 Hydrogenation on Ni Revisited

JFM Simons, TJ de Heer, RCJ van de Poll… - Journal of the …, 2023 - ACS Publications
Despite the large number of studies on the catalytic hydrogenation of CO2 to CO and
hydrocarbons by metal nanoparticles, the nature of the active sites and the reaction …

Synergistic Catalysis at the Ni/ZrO2–x Interface toward Low-Temperature CO2 Methanation

H Wang, Z Li, G Cui, M Wei - ACS Applied Materials & Interfaces, 2023 - ACS Publications
The CO2 methanation reaction, which achieves the carbon cycle and gains value-added
chemicals, has attracted much attention, but the design and exploitation of highly active …

CO2 Hydrogenation on Unpromoted and M-Promoted Co/TiO2 Catalysts (M = Zr, K, Cs): Effects of Crystal Phase of Supports and Metal–Support Interaction on …

W Li, G Zhang, X Jiang, Y Liu, J Zhu, F Ding, Z Liu… - ACS …, 2019 - ACS Publications
Cobalt catalysts supported on TiO2 with different crystal forms (anatase and rutile) differ
sharply in CO2 conversion and product selectivity for CO2 hydrogenation. The Co/rutile …

Ni–In Synergy in CO2 Hydrogenation to Methanol

J Zhu, F Cannizzaro, L Liu, H Zhang, N Kosinov… - ACS …, 2021 - ACS Publications
Indium oxide (In2O3) is a promising catalyst for selective CH3OH synthesis from CO2 but
displays insufficient activity at low reaction temperatures. By screening a range of promoters …

Tandem Catalysis for CO2 Hydrogenation to C2–C4 Hydrocarbons

C Xie, C Chen, Y Yu, J Su, Y Li, GA Somorjai… - Nano …, 2017 - ACS Publications
Conversion of carbon dioxide to C2–C4 hydrocarbons is a major pursuit in clean energy
research. Despite tremendous efforts, the lack of well-defined catalysts in which the spatial …

Tuning CO2 hydrogenation selectivity via metal-oxide interfacial sites

B Yan, B Zhao, S Kattel, Q Wu, S Yao, D Su, JG Chen - Journal of Catalysis, 2019 - Elsevier
CO 2 hydrogenation over ZrO 2-supported NiFe catalysts is investigated to illustrate the role
of Fe in controlling the activity and selectivity, and to reveal the structure-function …

Tuning selectivity of CO 2 hydrogenation by modulating the strong metal–support interaction over Ir/TiO 2 catalysts

Y Zhang, Z Zhang, X Yang, R Wang, H Duan… - Green …, 2020 - pubs.rsc.org
Exploration of highly selective catalysts for CO2 hydrogenation remains a great challenge
since the reduction of CO2 over the supported metal catalysts may give rise to various …

Optimizing Active Sites for High CO Selectivity during CO2 Hydrogenation over Supported Nickel Catalysts

TS Galhardo, AH Braga, BH Arpini… - Journal of the …, 2021 - ACS Publications
Controlling the selectivity of CO2 hydrogenation catalysts is a fundamental challenge. In this
study, the selectivity of supported Ni catalysts prepared by the traditional impregnation …

Overturning CO2 Hydrogenation Selectivity with High Activity via Reaction-Induced Strong Metal–Support Interactions

H Xin, L Lin, R Li, D Li, T Song, R Mu… - Journal of the …, 2022 - ACS Publications
Encapsulation of metal nanoparticles by support-derived materials known as the classical
strong metal–support interaction (SMSI) often happens upon thermal treatment of supported …