X Wang, X Chen, W Lin, P Li… - Advanced Synthesis & …, 2022 - Wiley Online Library
Axially chiral allenes occur on a wide range of natural products and synthetic molecules with significant biological activity. Furthermore, they are versatile building blocks in organic …
WD Chu, Y Zhang, J Wang - Catalysis Science & Technology, 2017 - pubs.rsc.org
Allene moieties with axial chirality are featured in many natural products with biological activities. They also serve as unique building blocks in organic synthesis and as chiral …
Chiral allenes, which exist widely in natural products, bioactive pharmaceuticals, and advanced functional materials, have received considerable attention from chemists. They …
M Ogasawara - Tetrahedron: asymmetry, 2009 - Elsevier
The conventional procedures for preparing optically active axially chiral allenes generally require stoichiometric chiral sources as either substrates or reagents. On the other hand …
A Hoffmann‐Röder, N Krause - … Chemie International Edition, 2002 - Wiley Online Library
In recent years, allenes have gained increasing attraction as interesting building blocks in modern organic chemistry. Their synthetic utility is not only demonstrated by an abundance …
J Ye, S Ma - Organic Chemistry Frontiers, 2014 - pubs.rsc.org
While one-carbon central chirality of organic molecules has been recognized and extensively studied for more than a century, far less attention has been paid to three-carbon …
T Hashimoto, K Sakata, F Tamakuni, MJ Dutton… - Nature Chemistry, 2013 - nature.com
Allenes are molecules based on three carbons connected by two cumulated carbon–carbon double bonds. Given their axially chiral nature and unique reactivity, substituted allenes …
Y Jiang, AB Diagne, RJ Thomson… - Journal of the American …, 2017 - ACS Publications
Allenes are useful functional groups in synthesis as a result of their inherent chemical properties and established reactivity patterns. One property of chemical bonding renders 1 …
D Qian, LL Wu, Z Lin, J Sun - Nature Communications, 2017 - nature.com
Although chiral allene preparation via formal SN2'nucleophilic substitutions of enantioenriched propargylic derivatives or metal-catalyzed reactions of racemic propargylic …