Recent advances in the catalytic syntheses of allenes: a critical assessment

RK Neff, DE Frantz - ACS Catalysis, 2014 - ACS Publications
The increasing synthetic utility of allenes in organic synthesis combined with their
incorporation into a growing list of natural products and active pharmaceutical ingredients …

Recent advances in organocatalytic enantioselective synthesis of axially chiral allenes

X Wang, X Chen, W Lin, P Li… - Advanced Synthesis & …, 2022 - Wiley Online Library
Axially chiral allenes occur on a wide range of natural products and synthetic molecules with
significant biological activity. Furthermore, they are versatile building blocks in organic …

Recent advances in catalytic asymmetric synthesis of allenes

WD Chu, Y Zhang, J Wang - Catalysis Science & Technology, 2017 - pubs.rsc.org
Allene moieties with axial chirality are featured in many natural products with biological
activities. They also serve as unique building blocks in organic synthesis and as chiral …

Recent advances in the metal-catalyzed asymmetric synthesis of chiral allenes

W Xiao, J Wu - Organic Chemistry Frontiers, 2022 - pubs.rsc.org
Chiral allenes, which exist widely in natural products, bioactive pharmaceuticals, and
advanced functional materials, have received considerable attention from chemists. They …

Catalytic enantioselective synthesis of axially chiral allenes

M Ogasawara - Tetrahedron: asymmetry, 2009 - Elsevier
The conventional procedures for preparing optically active axially chiral allenes generally
require stoichiometric chiral sources as either substrates or reagents. On the other hand …

[引用][C] Enantioselective Synthesis of and with Allenes

A Hoffmann‐Röder, N Krause - … Chemie International Edition, 2002 - Wiley Online Library
In recent years, allenes have gained increasing attraction as interesting building blocks in
modern organic chemistry. Their synthetic utility is not only demonstrated by an abundance …

Conquering three-carbon axial chirality of allenes

J Ye, S Ma - Organic Chemistry Frontiers, 2014 - pubs.rsc.org
While one-carbon central chirality of organic molecules has been recognized and
extensively studied for more than a century, far less attention has been paid to three-carbon …

Phase-transfer-catalysed asymmetric synthesis of tetrasubstituted allenes

T Hashimoto, K Sakata, F Tamakuni, MJ Dutton… - Nature Chemistry, 2013 - nature.com
Allenes are molecules based on three carbons connected by two cumulated carbon–carbon
double bonds. Given their axially chiral nature and unique reactivity, substituted allenes …

Enantioselective synthesis of allenes by catalytic traceless petasis reactions

Y Jiang, AB Diagne, RJ Thomson… - Journal of the American …, 2017 - ACS Publications
Allenes are useful functional groups in synthesis as a result of their inherent chemical
properties and established reactivity patterns. One property of chemical bonding renders 1 …

Organocatalytic synthesis of chiral tetrasubstituted allenes from racemic propargylic alcohols

D Qian, LL Wu, Z Lin, J Sun - Nature Communications, 2017 - nature.com
Although chiral allene preparation via formal SN2'nucleophilic substitutions of
enantioenriched propargylic derivatives or metal-catalyzed reactions of racemic propargylic …