Impact of VUV photons on SiO2 and organosilicate low-k dielectrics: General behavior, practical applications, and atomic models

MR Baklanov, V Jousseaume, TV Rakhimova… - Applied Physics …, 2019 - pubs.aip.org
This paper presents an in-depth overview of the application and impact of UV/VUV light in
advanced interconnect technology. UV light application in BEOL historically was mainly …

The effects of vacuum ultraviolet radiation on low-k dielectric films

H Sinha, H Ren, MT Nichols, JL Lauer… - Journal of Applied …, 2012 - pubs.aip.org
Plasmas, known to emit high levels of vacuum ultraviolet (VUV) radiation, are used in the
semiconductor industry for processing of low-k organosilicate glass (SiCOH) dielectric …

Synergistic damage effects of vacuum ultraviolet photons and O2 in SiCOH ultra-low-k dielectric films

J Lee, DB Graves - Journal of Physics D: Applied Physics, 2010 - iopscience.iop.org
Damage incurred during plasma processing, leading to increases in dielectric constant k, is
a persistent problem with porous ultra-low-k dielectric films, such as SiCOH. Although most …

The effect of VUV radiation from Ar/O2 plasmas on low-k SiOCH films

J Lee, DB Graves - Journal of physics D: Applied physics, 2011 - iopscience.iop.org
The degradation of porous low-k materials, like SiOCH, under plasma processing continues
to be a problem in the next generation of integrated-circuit fabrication. Due to the exposure …

Optical property changes in low-k films upon ultraviolet-assisted curing

S Eslava, G Eymery, P Marsik, F Iacopi… - Journal of the …, 2008 - iopscience.iop.org
Ultraviolet-assisted curing (UV curing) has been applied recently to enhance the mechanical
properties of low-films. Knowledge about which UV energies are most effective is still limited …

Roles of plasma-generated vacuum-ultraviolet photons and oxygen radicals in damaging nanoporous low-k films

J Lee, DB Graves - Journal of Vacuum Science & Technology A, 2013 - pubs.aip.org
One important class of low-k materials used as interconnect dielectrics employs methyl
groups added to nanoporous SiO 2 matrices. These carbon-doped oxide materials are …

Low-k films modification under EUV and VUV radiation

TV Rakhimova, AT Rakhimov… - Journal of Physics D …, 2013 - iopscience.iop.org
Modification of ultra-low-k films by extreme ultraviolet (EUV) and vacuum ultraviolet (VUV)
emission with 13.5, 58.4, 106, 147 and 193 nm wavelengths and fluences up to 6× 10 18 …

Ultraviolet irradiation effect on the properties of leakage current and dielectric breakdown of low-dielectric-constant SiOC (H) films using comb capacitor structure

CY Kim, R Navamathavan, HS Lee, JK Woo, MT Hyun… - Thin Solid Films, 2011 - Elsevier
Low-dielectric constant SiOC (H) films were deposited on p-type Si (100) substrates by
plasma-enhanced chemical-vapor deposition (PECVD) using dimethyldimethoxy silane …

Fundamental mechanisms of oxygen plasma-induced damage of ultralow-k organosilicate materials: The role of thermal P3 atomic oxygen

M Chaudhari, J Du, S Behera, S Manandhar… - Applied Physics …, 2009 - pubs.aip.org
Fourier transform infrared (FTIR) spectroscopy, x-ray photoelectron spectroscopy (XPS), and
ab initio density functional theory-based molecular dynamics simulations demonstrate …

Damage mechanism in low-dielectric (low-k) films during plasma processes

B Jinnai, T Nozawa, S Samukawa - Journal of Vacuum Science & …, 2008 - pubs.aip.org
Plasma is extensively used for the etching/ashing of low-dielectric (low-k⁠) films. However,
since low-k films, such as SiOC films, are vulnerable to plasma irradiation, they are severely …