Room‐Temperature Symmetric Giant Positive and Negative Electrocaloric Effect in PbMg0.5W0.5O3 Antiferroelectric Ceramic

J Li, HH Wu, J Li, X Su, R Yin, S Qin… - Advanced Functional …, 2021 - Wiley Online Library
As an emerging solid‐state refrigeration technology with zero‐emission and high energy
conversion efficiency, there is a compelling need for ferroelectric materials with giant …

Giant Negative Electrocaloric Effect in (Pb,La)(Zr,Sn,Ti)O3 Antiferroelectrics Near Room Temperature

F Zhuo, Q Li, J Gao, Y Ji, Q Yan, Y Zhang… - … applied materials & …, 2018 - ACS Publications
(Pb0. 97La0. 02)(Zr x Sn0. 94–x Ti0. 06) O3 (PLZST) antiferroelectric ceramics with x= 0.75–
0.90 have been fabricated and found to be a novel electrocaloric material system with a …

Giant electrocaloric effect and ultrahigh refrigeration efficiency in antiferroelectric ceramics by morphotropic phase boundary design

J Li, J Li, HH Wu, S Qin, X Su, Y Wang… - … Applied Materials & …, 2020 - ACS Publications
Electrocaloric effect (ECE) in ferroelectric (FE)/antiferroelectric (AFE) materials offers a
promising high-efficient and zero-emission solid-state cooling technology, whose materials …

Colossal negative electrocaloric effects in lead-free bismuth ferrite-based bulk ferroelectric perovskite for solid-state refrigeration

N Liu, R Liang, G Zhang, Z Zhou, S Yan, X Li… - Journal of Materials …, 2018 - pubs.rsc.org
The electrocaloric effect (ECE) provides a novel route to realize eco-friendly cooling, whose
cooling efficiency could be further enhanced by integrating the positive and negative ECE …

Giant Negative Electrocaloric Effect in Antiferroelectric La‐Doped Pb(ZrTi)O3 Thin Films Near Room Temperature

W Geng, Y Liu, X Meng, L Bellaiche, JF Scott… - Advanced …, 2015 - Wiley Online Library
Antiferroelectric thin films are demonstrated as a new class of giant electrocaloric materials
that exhibit a negative electrocaloric response of about− 5 K near room temperature. The …

Giant negative electrocaloric effect in antiferroelectric PbZrO 3 thin films in an ultra-low temperature range

M Guo, M Wu, W Gao, B Sun, X Lou - Journal of Materials Chemistry C, 2019 - pubs.rsc.org
Antiferroelectric thin films have demonstrated an excellent negative electrocaloric effect, and
are potential candidates for future refrigeration applications. In this study, the electrocaloric …

A metal-free molecular antiferroelectric material showing high phase transition temperatures and large electrocaloric effects

H Xu, W Guo, J Wang, Y Ma, S Han, Y Liu… - Journal of the …, 2021 - ACS Publications
Antiferroelectric (AFE) materials, featuring an antiparallel alignment of electric dipoles in the
adjacent sublattices, are keeping a great promise toward solid-state refrigeration …

[HTML][HTML] Perovskite ferroelectrics and relaxor-ferroelectric solid solutions with large intrinsic electrocaloric response over broad temperature ranges

H Khassaf, JV Mantese, N Bassiri-Gharb… - Journal of Materials …, 2016 - pubs.rsc.org
Electrocaloric materials have emerged as a viable technology for solid state heating/cooling
and waste heat recovery applications. We determine here intrinsic electrocaloric (EC) …

Superior energy storage density and giant negative electrocaloric effects in (Pb0. 98La0. 02)(Zr, Sn) O3 antiferroelectric ceramics

P Zhao, S Wang, H Tang, X Jian, X Zhao, Y Yao, T Tao… - Scripta Materialia, 2021 - Elsevier
Antiferroelectric materials are demanded in energy storage and solid-state cooling devices
due to their distinct hysteresis loops and phase transition behaviors. In this work,(Pb 0.98 La …

A Giant Electrocaloric Effect in Nanoscale Antiferroelectric and Ferroelectric Phases Coexisting in a Relaxor Pb0.8Ba0.2ZrO3 Thin Film at Room Temperature

B Peng, H Fan, Q Zhang - Advanced Functional Materials, 2013 - Wiley Online Library
Recently, large electrocaloric effects (ECE) in antiferroelectric sol‐gel PbZr0. 95Ti0. 05O3
thin films and in ferroelectric polymer P (VDF‐TrFE) 55/45 thin films were observed near the …