Visible light-induced selenylative spirocyclization of biaryl ynones toward the formation of selenated spiro [5.5] trienones

Z Chen, X Zheng, SF Zhou, X Cui - Organic & Biomolecular Chemistry, 2022 - pubs.rsc.org
A visible-light induced dearomative cascade cyclization of biaryl ynones with diselenides
under photocatalyst and external additive-free conditions has been explored, giving a series …

Visible Light‐Induced Synthetic Approach for Selenylative Spirocyclization of N‐Aryl Alkynamides with Molecular Oxygen as Oxidant

H Sahoo, A Mandal, S Dana… - Advanced Synthesis & …, 2018 - Wiley Online Library
A visible light‐induced (blue LED) radical cascade has been devised to effect selenylative
spirocyclization of N‐aryl alkynamides at room temperature under oxygen atmosphere and …

Visible-light mediated diarylselenylative cyclization of 1, 6-enynes

H Hou, Y Sun, Y Pan, H Yu, Y Han, Y Shi… - The Journal of …, 2020 - ACS Publications
We herein described a selenylative cyclization reaction of enynes by the utilization of
diselenides as radical sources. The visible-light irradiation of the reaction mixture enables …

Visible light-induced tandem oxidative cyclization of 2-alkynylanilines with disulfides (diselenides) to 3-sulfenyl-and 3-selenylindoles under transition metal-free and …

Q Shi, P Li, Y Zhang, L Wang - Organic Chemistry Frontiers, 2017 - pubs.rsc.org
A simple and efficient strategy for the synthesis of 3-sulfenyl and 3-selenyl indoles via a
visible light-induced tandem cyclization of 2-alkynylanilines with disulfides (diselenides) was …

Metal-free switchable ortho/ipso-cyclization of N-aryl alkynamides: divergent synthesis of 3-selenyl quinolin-2-ones and azaspiro [4, 5] trienones

H Sahoo, GS Grandhi, I Ramakrishna… - Organic & Biomolecular …, 2019 - pubs.rsc.org
A selenium radical triggered switchable ortho/ipso-cyclization cascade of N-aryl
alkynamides has been devised under metal-free conditions to access 3-selenyl quinolin-2 …

Visible Light Assisted Selenylative Intramolecular Dearomative Carbo‐Spirocyclisation (IDCS) of Homologated‐Ynones

SR Sahoo, B Das, D Sarkar, F Henkel… - European Journal of …, 2020 - Wiley Online Library
A visible light assisted dearomative selenylative carbo‐spirocyclisation of aromatic
homologated‐ynones has been reported. The ynones deliver selenylative spiro …

Radical selenylative cyclization of trifluoromethyl propargyl imines for the synthesis of trifluoromethyl-and seleno-azaspiro [4, 5]-tetraenones and quinolines

G Wei, J Zhang, H Wang, Z Chen, XF Wu - Organic & Biomolecular …, 2023 - pubs.rsc.org
A radical selenylative cyclization of trifluoromethyl propargyl imines with diselenides for the
regiodivergent construction of diversely functionalized azaspiro [4, 5]-tetraenones and …

Selenium radical mediated cascade cyclization: concise synthesis of selenated benzofurans (benzothiophenes)

C An, CY Li, XB Huang, WX Gao, YB Zhou, MC Liu… - Organic …, 2019 - ACS Publications
Presented in this work is a novel methodology for the synthesis of selenated benzofurans (or
benzothiophenes) via AgNO2-catalyzed radical cyclization of 2-alkynylanisoles (or 2 …

Selectfluor-mediated construction of 3-arylselenenyl and 3, 4-bisarylselenenyl spiro [4.5] trienones via cascade annulation of N-phenylpropiolamides with diselenides

JW Yuan, Q Chen, WT Wu, JJ Zhao, LR Yang… - New Journal of …, 2022 - pubs.rsc.org
A cascade annulation of terminal alkynyl amides with diselenides leading to the construction
of 3-arylselenenyl spiro [4.5] trienones was realized under mild conditions with Selectfluor …

Synthesis of β-Selenylated Cyclopentanones via Photoredox-Catalyzed Selenylation/Ring-Expansion Cascades of Alkenyl Cyclobutanols

H Im Jung, DY Kim - Synlett, 2019 - thieme-connect.com
A photoredox strategy to access β-selenated cyclic ketone derivatives through the coupling
reaction of 1-(1-arylvinyl) cyclobutanols with diselenides under blue LED irradiation and an …