Role of Pairwise Reactions on the Synthesis of Li0.3La0.57TiO3 and the Resulting Structure–Property Correlations

TF Malkowski, RL Sacci, RD McAuliffe… - Inorganic …, 2021 - ACS Publications
The performance of single-ion conductors is highly sensitive to the material's defect
chemistry. Tuning these defects is limited for solid-state reactions as they occur at particle …

Memory Effect on the Synthesis of Perovskite-Type Li-Ion Conductor LixLa2/3–x/3TiO3 (LLTO)

MS Chambers, J Chen, RL Sacci… - Chemistry of …, 2024 - ACS Publications
The structural chemistry of the solid ion-conducting Li x La2/3–x/3TiO3 (LLTO) is rich with
various polymorphs related to atomic segregation. We explored the LLTO reaction pathway …

Intrinsic layered defects in solid-state electrolyte Li0. 33La0. 56TiO3

S Peng, Y Chen, B Wang, X Zhou, H Yu, J Wang… - Materials Today …, 2022 - Elsevier
Abstract Perovskite La 2/3-x Li 3x TiO 3 is a typical solid-state electrolyte for all-solid-state
lithium-ion batteries. The material system has been intensively studied because of its high …

[HTML][HTML] Elucidating the nature of grain boundary resistance in lithium lanthanum titanate

AR Symington, M Molinari, JA Dawson… - Journal of Materials …, 2021 - pubs.rsc.org
Solid electrolytes for all-solid-state batteries are generating remarkable research interest as
a means to improve the safety, stability and performance of rechargeable batteries. Solid …

Atomic defect mediated Li-ion diffusion in a lithium lanthanum titanate solid-state electrolyte

L Zhang, L Xu, Y Nian, W Wang, Y Han, L Luo - ACS nano, 2022 - ACS Publications
Lithium lanthanum titanium oxide (LLTO) as a fast Li-ion conductor is a promising candidate
for future all-solid-state Li batteries. Fundamental understanding of the microstructure of …

In situ atomic-scale engineering of the chemistry and structure of the grain boundaries region of Li3xLa2/3-xTiO3

X He, S Li, G Cao, J Hu, J Zhang, R Qiao, J Pan… - Scripta Materialia, 2020 - Elsevier
Severe deviation in structure and chemistry at grain boundaries has been regarded as the
source of the poor conductivity of Li 3 x La 2/3-x TiO 3. In this work, we report an in situ grain …

A correlation between formation enthalpy and ionic conductivity in perovskite-structured Li 3x La 0.67− x TiO 3 solid lithium ion conductors

X Guo, PS Maram, A Navrotsky - Journal of Materials Chemistry A, 2017 - pubs.rsc.org
Perovskite-structured lithium lanthanum titanate (LLTO) Li3xLa0. 67− xTiO3 (compositions
x= 0.04 to 0.15) has been prepared by conventional solid state reaction. The phase purity …

[HTML][HTML] Thermally-driven reactivity of Li 0.35 La 0.55 TiO 3 solid electrolyte with LiCoO 2 cathode

S Chandra, Y Kim, D Vivona, I Waluyo… - Journal of materials …, 2022 - pubs.rsc.org
A critical bottleneck for developing successful solid-state batteries is minimizing the
interfacial impedances between the solid electrolyte and the active electrode materials …

Enhanced Li+ conduction in perovskite Li 3x La 2/3− x□ 1/3− 2x TiO 3 solid-electrolytes via microstructural engineering

WJ Kwon, H Kim, KN Jung, W Cho, SH Kim… - Journal of materials …, 2017 - pubs.rsc.org
Solid electrolytes are key to the evolution of all-solid-state lithium batteries as next-
generation energy storage systems. High ionic conductivity and stability of solid electrolytes …

Structural origin of low Li-ion conductivity in perovskite solid-state electrolyte

L Xu, L Zhang, Y Hu, L Luo - Nano Energy, 2022 - Elsevier
Perovskite solid-state electrolyte, Lithium Lanthanum Titanium Oxide, has long been
considered as a promising candidate enabling all-solid-state Li batteries due to its high bulk …